Understanding the electric double-layer structure, capacitance, and charging dynamics
J Wu - Chemical Reviews, 2022 - ACS Publications
Significant progress has been made in recent years in theoretical modeling of the electric
double layer (EDL), a key concept in electrochemistry important for energy storage …
double layer (EDL), a key concept in electrochemistry important for energy storage …
Understanding specific ion effects and the Hofmeister series
KP Gregory, GR Elliott, H Robertson, A Kumar… - Physical Chemistry …, 2022 - pubs.rsc.org
Specific ion effects (SIE), encompassing the Hofmeister Series, have been known for more
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
Insights into ionic liquids: From Z-bonds to quasi-liquids
Ionic liquids (ILs) hold great promise in the fields of green chemistry, environmental science,
and sustainable technology due to their unique properties, such as a tailorable structure, the …
and sustainable technology due to their unique properties, such as a tailorable structure, the …
Interfacial layering in the electric double layer of ionic liquids
Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly interacting
environment, leading to the formation of discrete layers of charges at interfaces and spin …
environment, leading to the formation of discrete layers of charges at interfaces and spin …
Theory of ion aggregation and gelation in super-concentrated electrolytes
In concentrated electrolytes with asymmetric or irregular ions, such as ionic liquids and
solvent-in-salt electrolytes, ion association is more complicated than simple ion-pairing …
solvent-in-salt electrolytes, ion association is more complicated than simple ion-pairing …
Correlation length in concentrated electrolytes: Insights from all-atom molecular dynamics simulations
We study the correlation length of the charge–charge pair correlations in concentrated
electrolyte solutions by means of all-atom, explicit-solvent molecular dynamics simulations …
electrolyte solutions by means of all-atom, explicit-solvent molecular dynamics simulations …
Ion clusters and networks in water-in-salt electrolytes
Water-in-salt electrolytes (WiSEs) are a class of super-concentrated electrolytes that have
shown much promise in replacing organic electrolytes in lithium-ion batteries. At the …
shown much promise in replacing organic electrolytes in lithium-ion batteries. At the …
A multiple decay-length extension of the Debye–Hückel theory: to achieve high accuracy also for concentrated solutions and explain under-screening in dilute …
R Kjellander - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
The Poisson–Boltzmann and Debye–Hückel approximations for the pair distributions and
mean electrostatic potential in electrolytes predict that these entities have one single decay …
mean electrostatic potential in electrolytes predict that these entities have one single decay …
Ionic layering and overcharging in electrical double layers in a Poisson-Boltzmann model
Electrical double layers (EDLs) play a significant role in a broad range of physical
phenomena related to colloidal stability, diffuse-charge dynamics, electrokinetics, and …
phenomena related to colloidal stability, diffuse-charge dynamics, electrokinetics, and …
Noether's second theorem and covariant field theory of mechanical stresses in inhomogeneous ionic liquids
PE Brandyshev, YA Budkov - The Journal of chemical physics, 2023 - pubs.aip.org
In this paper, we present a covariant approach that utilizes Noether's second theorem to
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …