Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …

Metal complexes of multi‐porphyrins and multi‐corroles are unique systems that display a
host of extremely interesting properties. Availability of free meso and β positions allow …

For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …

Multiple lines of evidence, including electronic absorption spectroscopy, infrared
spectroscopy, and broken-symmetry DFT calculations, indicate that the well-known FeNO …

Macrocycles such as porphyrins and corroles have important functions in chemistry and
biology, including light absorption for photosynthesis. Generation of near‐IR (NIR) …

Three new iridium (III) corrole complexes, having symmetrically and asymmetrically
substituted corrole frameworks and judiciously varied axial ligands are prepared and …

The first FeNO octabromocorroles have been synthesized including four β-octabromo-meso-
tris (pX-phenyl) corrole derivatives Fe [Br8TpXPC](NO)(X= CF3, H, CH3, OCH3) and the β …

Sharpless et al. have described, while performing the molybdenum-catalyzed epoxidation
reaction of olefins using alkyl hydroperoxides, that the molybdenum-oxo moiety is an active …