Current nature-based biological practices for rare earth elements extraction and recovery: Bioleaching and biosorption

RM Brown, A Mirkouei, D Reed, V Thompson - Renewable and Sustainable …, 2023 - Elsevier
There is a growing demand for advancing products and renewable technologies worldwide
that rely on rare earth elements (REEs), including those directly necessary for a low-carbon …

Research progress of rare earth separation methods and technologies

M Traore, A Gong, Y Wang, L Qiu, Y Bai, W Zhao… - Journal of Rare …, 2023 - Elsevier
Strategical elements, such as rare earth elements, play a crucial role in the industry,
especially in producing high-tech materials. Major global industries have developed a …

Size selective ligand tug of war strategy to separate rare earth elements

KR Johnson, DM Driscoll, JT Damron, AS Ivanov… - JACS Au, 2023 - ACS Publications
Separating rare earth elements is a daunting task due to their similar properties. We report a
“tug of war” strategy that employs a lipophilic and hydrophilic ligand with contrasting …

Elucidating the speciation of extracted lanthanides by diglycolamides

AA Peroutka, SS Galley, JC Shafer - Coordination Chemistry Reviews, 2023 - Elsevier
Many studies over the past few decades have been devoted to addressing the application of
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …

Advancing rare-earth separation by machine learning

T Liu, KR Johnson, S Jansone-Popova, D Jiang - JACS Au, 2022 - ACS Publications
Constituting the bulk of rare-earth elements, lanthanides need to be separated to fully
realize their potential as critical materials in many important technologies. The discovery of …

Molecular forces in liquid–liquid extraction

M Špadina, JF Dufrêche, S Pellet-Rostaing… - Langmuir, 2021 - ACS Publications
The phase transfer of ions is driven by gradients of chemical potentials rather than
concentrations alone (ie, by both the molecular forces and entropy). Extraction is a …

Aqueous Structure of Lanthanide–EDTA Coordination Complexes Determined by a Combined DFT/EXAFS Approach

A Smerigan, S Biswas, FD Vila, J Hong… - Inorganic …, 2023 - ACS Publications
Sustainable production of rare earth elements (REEs) is critical for technologies needed for
climate change mitigation, including wind turbines and electric vehicles. However …

Modulating metal-centered dimerization of a lanthanide chaperone protein for separation of light lanthanides

WB Larrinaga, JJ Jung, CY Lin, AK Boal… - Proceedings of the …, 2024 - pnas.org
Elucidating details of biology's selective uptake and trafficking of rare earth elements,
particularly the lanthanides, has the potential to inspire sustainable biomolecular …

Mechanism and Kinetics of Ethanol–Acetaldehyde Conversion to 1, 3-Butadiene over Isolated Lewis Acid La Sites in Silanol Nests in Dealuminated Beta Zeolite

Y Zhang, L Qi, Y Li, T Yang, DM Meira, C Dun… - ACS …, 2024 - ACS Publications
Biomass-derived ethanol (EtOH) and acetaldehyde (AcH) conversion to 1, 3-butadiene (1, 3-
BD) is an alternative process for 1, 3-BD production. The present investigation reports the …

Critical fluctuations in liquid–liquid extraction organic phases controlled by extractant and diluent molecular structure

BL Bonnett, D Sheyfer, PN Wimalasiri… - Physical Chemistry …, 2023 - pubs.rsc.org
Extractant aggregation in liquid–liquid extraction organic phases impacts extraction
energetics and is related to the deleterious efficiency-limiting liquid–liquid phase transition …