Technical development of characterization methods provides insights into clay mineral-water interactions: A comprehensive review

G Wang, L Ran, J Xu, Y Wang, L Ma, R Zhu, J Wei… - Applied Clay …, 2021 - Elsevier
Clay mineral-water interactions are ubiquitous, and crucial to a variety of natural processes
including all aspects of geology, sedimentology, edaphology, geomorphology, seismology …

[图书][B] Handbook of layered materials

SM Auerbach, KA Carrado, PK Dutta - 2004 - taylorfrancis.com
Focusing on layered compounds at the core of materials intercalation chemistry, this
reference comprehensively explores clays and other classes of materials exhibiting the …

Molecular dynamics simulations of water and sodium diffusion in smectite interlayer nanopores as a function of pore size and temperature

M Holmboe, IC Bourg - The Journal of Physical Chemistry C, 2014 - ACS Publications
The diffusion coefficients (D) of water and solutes in nanoporous Na-smectite clay barriers
have been widely studied because of their importance in high-level radioactive waste …

Nanoscale Prediction of the Thermal, Mechanical, and Transport Properties of Hydrated Clay on 106- and 1015-Fold Larger Length and Time Scales

X Zheng, IC Bourg - ACS nano, 2023 - ACS Publications
Coupled thermal, hydraulic, mechanical, and chemical (THMC) processes, such as
desiccation-driven cracking or chemically driven fluid flow, significantly impact the …

Molecular dynamics simulation of thermal, hydraulic, and mechanical properties of bentonite clay at 298 to 373 K

X Zheng, TR Underwood, IC Bourg - Applied Clay Science, 2023 - Elsevier
Bentonite, a fine-grained geologic material rich in smectite clay, is considered for use in the
isolation of high-level radioactive waste (HLRW) because of its low hydraulic permeability …

Connecting the molecular scale to the continuum scale for diffusion processes in smectite-rich porous media

IC Bourg, G Sposito - Environmental science & technology, 2010 - ACS Publications
In this paper, we address the manner in which the continuum-scale diffusive properties of
smectite-rich porous media arise from their molecular-and pore-scale features. Our starting …

Tracer diffusion in compacted, water-saturated bentonite

IC Bourg, G Sposito, ACM Bourg - Clays and Clay Minerals, 2006 - cambridge.org
Compacted Na-bentonite clay barriers, widely used in the isolation of solid-waste landfills
and other contaminated sites, have been proposed for a similar use in the disposal of high …

Study on anisotropy of effective diffusion coefficient and activation energy for deuterated water in compacted sodium bentonite

S Suzuki, H Sato, T Ishidera, N Fujii - Journal of Contaminant Hydrology, 2004 - Elsevier
To quantify the effects of temperature on the diffusivity of deuterated water (HDO) in
compacted sodium bentonite, through-diffusion experiments were conducted at elevated …

[PDF][PDF] Absolute pore size distributions from NMR

GH Sørland, K Djurhuus, HC Widerøe, JR Lien… - 2007 - diffusion.uni-leipzig.de
NMR measurements on core samples saturated with brine returns valuable information on
the porous structure of the rock core. Monitoring a single fluid component in a relaxation …

Thermal and saline effect on mineral-water interactions in compacted clays: A NMR-based study

H Tian, C Wei, R Yan - Applied Clay Science, 2019 - Elsevier
The behavior of the confined pore water in three compacted clays, which are saturated with
different fluids at temperature ranging from 22 to 75° C, is investigated via the NMR …