Topotactic Hydrogen in Nickelate Superconductors and Akin Infinite-Layer Oxides

L Si, W Xiao, J Kaufmann, JM Tomczak, Y Lu, Z Zhong… - Physical review …, 2020 - APS
Superconducting nickelates appear to be difficult to synthesize. Since the chemical
reduction of ABO 3 [rare earth (A), transition metal (B)] with CaH 2 may result in both ABO 2 …

Is La3Ni2O6.5 a Bulk Superconducting Nickelate?

R Gao, L Jin, S Huyan, D Ni, H Wang… - … Applied Materials & …, 2024 - ACS Publications
Superconducting states onsetting at moderately high temperatures have been observed in
epitaxially stabilized RE NiO2-based thin films. However, recently, it has also been reported …

Magnetic correlations in infinite-layer nickelates: An experimental and theoretical multimethod study

RA Ortiz, P Puphal, M Klett, F Hotz, RK Kremer… - Physical Review …, 2022 - APS
We report a comprehensive study of magnetic correlations in LaNiO 2, a parent compound
of the recently discovered family of infinite-layer (IL) nickelate superconductors, using …

Enhanced Magnetic Interaction by Face-Shared Hydride Anions in 6H-BaCrO2H

K Higashi, M Ochi, Y Nambu, T Yamamoto… - Inorganic …, 2021 - ACS Publications
Studies on magnetic oxyhydrides have been almost limited to perovskite-based lattices with
corner-sharing octahedra with a M–H–M (M: transition metal) angle of θ∼ 180°. Using a …

Mesoporous Electrocatalysts with p–n Heterojunctions for Efficient Electroreduction of CO2 and N2 to Urea

L Ma, J Yuan, Z Liu, Y Luo, Y Su, K Zhu… - … Applied Materials & …, 2024 - ACS Publications
The electrocatalytic synthesis of high-value-added urea by activating N2 and CO2 is a green
synthesis technology that has achieved carbon neutrality. However, the chemical adsorption …

Locating anionic hydrogen in Ba3 (Yb, Lu) 2O5H2: A combined approach of X-ray diffraction, crystal chemistry, and DFT calculations

T Besara, DC Ramirez, J Sun, NW Falb, W Lan… - Journal of Solid State …, 2023 - Elsevier
By a combination of x-ray diffraction, structural chemistry, and DFT calculations, the
presence and location of anionic hydrogen in the two new, layered lanthanide oxyhydrides …

Hole and electron doping of topochemically reduced Ni (I)/Ru (II) insulating ferromagnetic oxides

Z Xu, L Jin, JK Backhaus, F Green… - Inorganic …, 2021 - ACS Publications
La x Sr2–x NiRuO6, La x Sr4–x NiRuO8, and La x Sr3–x NiRuO7 are, respectively, the n=∞,
1, and 2 members of the (La x/2Sr1–(x/2)) n Sr (Ni0. 5Ru0. 5) n O3 n+ 1 compositional …

Expanding the hydride chemistry: antiperovskites A 3 MO 4 H (A= Rb, Cs; M= Mo, W) introducing the transition oxometalate hydrides

A Mutschke, A Schulz, M Bertmer, C Ritter… - Chemical …, 2022 - pubs.rsc.org
The four compounds A3MO4H (A= Rb, Cs; M= Mo, W) are introduced as the first members of
the new material class of the transition oxometalate hydrides. The compounds are …

[PDF][PDF] The topochemical reduction of some complex iridium oxides

J Murrell - 2024 - ora.ox.ac.uk
The work presented in this thesis focuses on the topochemical reduction of Ir-containing
oxides with perovskite-type structures to form novel anion-deficient and mixed-anion …

Rank and signature classification of topochemical solid-state reactions

AM Tokmachev - CrystEngComm, 2021 - pubs.rsc.org
The rank and signature of the linear transformation between the reactant and product unit
cells are utilized to classify solid-state reactions. The classification is applicable to topotaxy …