Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Hydroxylation of aryl carbon–hydrogen bonds with transition metal catalysts has proven
challenging when oxygen is used as the oxidant. Here, we report a palladium complex …

Transition metal hydroxides of the late transition metals are now relatively common, and play
a special role in both the synthesis of new complexes and in important catalytic reactions …

Nickel-catalyzed cross-coupling reactions are experiencing a dramatic resurgence in recent
years given their ability to employ a wider range of electrophiles as well as promote …

Herein, we describe the development of a Rh-catalyzed C–H acyloxylation under mild
electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was …

The use of the tridentate ligand 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane (Me3tacn) and the
cyclic alkyl/aryl C-donor ligand-CH2CMe2-o-C6H4-(cycloneophyl) allows for the synthesis …

Efficient reduction of O2 to water is a central challenge in energy conversion and many
aerobic oxidation reactions. Here, we show that the electrochemical oxygen reduction …

Described herein is the synthesis of the NiII complex (t BuMe2tacn) NiII (cycloneophyl)(t
BuMe2tacn= 1-tert-butyl-4, 7-dimethyl-1, 4, 7-triazacyclononane, cycloneophyl=− CH2CMe2 …

This article describes an investigation of C (sp3)–O bond-forming reductive elimination
reactions from PdIV complexes. Phenoxide, acetate, difluoroacetate, dimethylphosphate …