Photo-and redox-driven artificial molecular motors

M Baroncini, S Silvi, A Credi - Chemical reviews, 2019 - ACS Publications
Directed motion at the nanoscale is a central attribute of life, and chemically driven motor
proteins are nature's choice to accomplish it. Motivated and inspired by such …

[HTML][HTML] Artificial molecular machines

S Erbas-Cakmak, DA Leigh, CT McTernan… - Chemical …, 2015 - ACS Publications
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …

Supramolecular ferroelectrics

AS Tayi, A Kaeser, M Matsumoto, T Aida, SI Stupp - Nature Chemistry, 2015 - nature.com
Supramolecular chemistry uses non-covalent interactions to coax molecules into forming
ordered assemblies. The construction of ordered materials with these reversible bonds has …

Crystalline porous organic salts

G Xing, D Peng, T Ben - Chemical Society Reviews, 2024 - pubs.rsc.org
Crystalline porous organic salts (CPOSs), formed by the self-assembly of organic acids and
organic bases through ionic bonding, possess definite structures and permanent porosity …

Fast motion of molecular rotors in metal–organic framework struts at very low temperatures

J Perego, S Bracco, M Negroni, CX Bezuidenhout… - Nature Chemistry, 2020 - nature.com
The solid state is typically not well suited to sustaining fast molecular motion, but in recent
years a variety of molecular machines, switches and rotors have been successfully …

Tunable and switchable dielectric constant in an amphidynamic crystal

W Zhang, HY Ye, R Graf, HW Spiess… - Journal of the …, 2013 - ACS Publications
The inclusion compound [(CH3) 2NH2] 2 [KCo (CN) 6] exhibits a marked temperature-
dependent dielectric constant and can be considered as a model of tunable and switchable …

Carboranes in the chemist's toolbox

RN Grimes - Dalton Transactions, 2015 - pubs.rsc.org
Once seldom encountered outside of a few laboratories, carboranes are now everywhere,
playing a role in the development of a broad range of technologies encompassing organic …

Wholly synthetic molecular machines

C Cheng, JF Stoddart - ChemPhysChem, 2016 - Wiley Online Library
The past quarter of a century has witnessed an increasing engagement on the part of
physicists and chemists in the design and synthesis of molecular machines de novo. This …

Molecular rotors built in porous materials

A Comotti, S Bracco, P Sozzani - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Molecules and materials can show dynamic structures in which the dominant
mechanism is rotary motion. The single mobile elements are defined as “molecular rotors” …

Metal-catalyzed B–H acylmethylation of pyridylcarboranes: access to carborane-fused indoliziniums and quinoliziniums

HJ Cao, X Wei, F Sun, X Zhang, C Lu, H Yan - Chemical Science, 2021 - pubs.rsc.org
Metal-catalyzed mono-acylmethylation of pyridylcarboranes has been realized using α-
carbonyl sulfoxonium ylides as a coupling partner. The reaction features high efficiency …