Structural chemistry of giant metal based supramolecules

AV Virovets, E Peresypkina, M Scheer - Chemical Reviews, 2021 - ACS Publications
The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism

YK Deng, HF Su, JH Xu, WG Wang… - Journal of the …, 2016 - ACS Publications
In search of functional molecular materials and the study of their formation mechanism, we
report the elucidation of a hierarchical step-by-step formation from monomer (Mn) to …

Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem II

ZJ Liu, XL Wang, C Qin, ZM Zhang, YG Li… - Coordination chemistry …, 2016 - Elsevier
Abstract The {Mn 4 O 5 Ca} cluster of photosystem II is a well-known cubane-like transition-
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …

A dodecanuclear heterometallic dysprosium–cobalt wheel exhibiting single-molecule magnet behaviour

LF Zou, L Zhao, YN Guo, GM Yu, Y Guo… - Chemical …, 2011 - pubs.rsc.org
A dodecanuclear heterometallic dysprosium–cobalt wheel exhibiting single-molecule magnet
behaviour - Chemical Communications (RSC Publishing) DOI:10.1039/C1CC12405F Royal …

Beyond clusters: supramolecular networks self‐assembled from nanosized silver clusters and inorganic anions

Z Wang, XY Li, LW Liu, SQ Yu, ZY Feng… - … A European Journal, 2016 - Wiley Online Library
Assembly of small clusters into rigid bodies with precise shape and symmetry has been
witnessed by the significant advances in cluster‐based metal–organic frameworks (MOFs) …

Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Macroscopic Hexagonal Tubes of 3 d–4 f Metallocycles

J Wu, L Zhao, L Zhang, XL Li, M Guo… - Angewandte …, 2016 - Wiley Online Library
The self‐assembly of three giant hexagonal 3d–4f metallocycles with inner diameters of
16.4, 16.5, and 16.4 Å, is described. Hexagonal metallocycles were stacked along the …

Accurate binding of porous aluminum molecular ring catalysts with the substrate

D Luo, H Xiao, MY Zhang, SD Li, L He, H Lv, CS Li… - Chemical …, 2023 - pubs.rsc.org
Metal molecular rings are a class of compounds with aesthetically pleasing symmetry and
fundamentally useful properties. The reported work generally focuses on the ring center …

Coordination clusters of 3d-metals that behave as single-molecule magnets (SMMs): synthetic routes and strategies

D Maniaki, E Pilichos, SP Perlepes - Frontiers in Chemistry, 2018 - frontiersin.org
The area of 3d-metal coordination clusters that behave as Single-Molecule Magnets (SMMs)
is now quite mature within the interdisciplinary field of Molecular Magnetism. This area has …