The discovery of ferrocene,[Fe (η5-C5H5) 2], seventy years ago has significantly influenced
chemical research and provided a key impetus for establishing and rapidly expanding …

Conspectus Persistent radicals are potential building blocks of novel materials in many
fields. Recently, highly stable persistent radicals are considered to be within reach, thanks to …

Inorganic metallocene derivatives containing only cyclo-P n ligands have been targeted for
more than 20 years, but their syntheses have never been achieved by pursuing the …

Electrochemistry, ferrocenate, ferrocene, organometallic chemistry, redox chemistry The
realization that ferrocene in polar organic solutions could overcome liquid junction potential …

A series of stable iron (II) bis (dicarbollide) derivatives [8, 8′-(RNHC (Et) HN) 2-3, 3′-Fe (1,
2-C2B9H10) 2](R= Pr, R= Ph,(CH2) 2OH,(CH2) 3OH,(CH2) 2NMe2) was prepared starting …

Here, we report the imidazolium-/pyrrolinium-substituted persistent zwitterionic ferrocenate
derivatives, which were characterized by electron paramagnetic resonance (EPR) and 57Fe …

A series of rare earth (mono) phospholide mixed sandwich complexes of the general form [M
(PC 4 R 4)(COT)(THF) n](M= Sc, Y, La, Lu; R= Me, Et; COT= cyclooctatetraenide,{C 8 H 8} 2 …

The β-diketiminate supporting group,[ArNCRCHCRNAr]−, stabilizes low coordination
number complexes. Four such complexes, where R= tert-butyl, Ar= 2, 6-diisopropylphenyl …

Since the first reports and structural characterisation of ferrocene in the 1950s, metallocenes
[M (Cp) 2](M= metal, Cp= cyclopentadienyl, C5H5) have become a workhorse of …

A series of heteroleptic rare earth (mono) phospholide sandwich complexes of the general
form [M (PC4R4)(COT)(THF) n](M= Sc, Y, La, Lu; R= Me, Et; COT= cyclooctatetraenide …