Recent advance in heterometallic nanomagnets based on TMxLn4− x cubane subunits

J Wang, M Feng, MN Akhtar, ML Tong - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract 3d-4f cubane-like complexes exhibit unique structural pattern, thus become a
fascinating subclass of 3d-4f complexes. In this review, we first present the structural …

{Mn6IIIMnIVDy2III} Single-Molecule Magnet Based on Cubane Subunits

M Darii, J van Leusen, VC Kravtsov… - Crystal Growth & …, 2023 - ACS Publications
A new mixed-valence heterometallic nonanuclear cluster [Mn7Dy2 (μ4-O) 2 (μ3-O) 4 (μ3-
OMe) 2 (μ2-OH)(piv) 8 (dea) 2 (MeOH) 2 (H2O) 2](NO3)· H2O (1)(where Hpiv= pivalic acid) …

A Zn-based Zig-Zag 1D chain type coordination polymer for removal of methylene blue dye from an aqueous solution

S Waseem, H Saleem, MN Akhtar, M Imran… - Inorganica Chimica …, 2024 - Elsevier
A 1D zig-zag zinc coordination chain,[Zn (piv) 2] n (1)(where piv= pivalic acid) has been
synthesized by a reaction of ZnCl 2 with O-donor pivalic acid in the mixed solvent system …

Heterometallic (3d-4f) coordination clusters with unique topology: self-assembly synthesis, structural features, and magnetic properties

MN Akhtar, MA AlDamen, J Khan, M Shahid… - Crystal Growth & …, 2020 - ACS Publications
Three heterometallic Fe6Ln4 clusters were self-assembled by using N-
methyldiethanolamine (H2mdea) and 3, 5-dinitrobenzoic acid (Hdnbz) as principal building …

Cationic dye adsorption and separation at discrete molecular level: first example of an iron cluster with rapid and selective adsorption of methylene blue from aqueous …

MN Akhtar, I Mantasha, M Shahid… - New Journal of …, 2021 - pubs.rsc.org
A hexanuclear iron (III) complex,[Fe6III (μ3-O)(edteH) 2 (piv) 6 (N3) 2](1), was prepared by
the reaction of FeCl2· 4H2O with N, N, N′, N′-tetrakis (2-hydroxyethyl) ethylenediamine …

Synergetic magnetic and luminescence switching via solid state phase transitions of the dysprosium–dianthracene complex

JC Liu, XD Huang, Q Zou, SS Bao, XZ Wang… - Journal of Materials …, 2020 - pubs.rsc.org
Manipulating the synergy between magnetic and optical characteristics in a predictable
manner by an external stimulus is a highly desirable option to develop smart materials for …

Heterometallic 3d–4f Alkoxide Precursors for the Synthesis of Binary Oxide Nanomaterials

R Petrus, A Kowaliński, J Utko, K Matuszak… - Inorganic …, 2023 - ACS Publications
In this study, a new method for the synthesis of heterometallic 3d–4f alkoxides by the direct
reaction of metallic lanthanides (La, Pr, Nd, Gd) with MCl2 (M= Mn, Ni, Co) in 2 …

Interplay of anthracene luminescence and dysprosium magnetism by steric control of photodimerization

XD Huang, JG Jia, M Kurmoo, SS Bao… - Dalton Transactions, 2019 - pubs.rsc.org
Systematic control of the intermolecular pair-wise [4+ 4] photocycloaddition of a series of
dysprosium phosphonates through fine-tuning of two different phosphonate ligands, one …

The effect of the orientation of the Jahn–Teller distortion on the magnetic interactions of trinuclear mixed-valence Mn (II)/Mn (III) complexes

R Bikas, E Shahmoradi, S Reinoso, M Emami… - Dalton …, 2019 - pubs.rsc.org
Two new trinuclear manganese complexes,[Mn3 (L1)(μ-OCH3) 2 (N3) 2]· CH3OH (1) and
[Mn3 (L2)(μ-OCH3) 2 (N3) 2]· CH3OH (2), have been obtained from the reaction of Mn (OAc) …

Synthesis, crystal structure, DFT calculations, molecular docking study and Hirshfeld surface analysis of alkoxido-bridged dinuclear iron (III) complex

MN Akhtar, MA AlDamen, W Zierkiewicz… - Research on Chemical …, 2020 - Springer
Abstract Reaction of FeCl 2· 4H 2 O, NaN 3 and N, N′-bis (2-hydroxyethyl)-
ethylenediamine (heenH 2) in a CH 3 CN/CH 2 Cl 2 solution resulted in a dinuclear …