Hydrothermal treatment of biomass feedstocks for sustainable production of chemicals, fuels, and materials: progress and perspectives

B Zhang, BK Biswal, J Zhang… - Chemical …, 2023 - ACS Publications
Hydrothermal process is an emerging technology that contributes to sustainable production
of biomass-derived chemicals, fuels, and materials. This technology uses hot compressed …

Recent advances in the catalytic depolymerization of lignin towards phenolic chemicals: a review

X Liu, FP Bouxin, J Fan, VL Budarin, C Hu… - …, 2020 - Wiley Online Library
The efficient valorization of lignin could dictate the success of the 2nd generation biorefinery.
Lignin, accounting for on average a third of the lignocellulosic biomass, is the most …

Wood hemicelluloses exert distinct biomechanical contributions to cellulose fibrillar networks

J Berglund, D Mikkelsen, BM Flanagan, S Dhital… - Nature …, 2020 - nature.com
Hemicelluloses, a family of heterogeneous polysaccharides with complex molecular
structures, constitute a fundamental component of lignocellulosic biomass. However, the …

A critical review on the analysis of lignin carbohydrate bonds

N Giummarella, Y Pu, AJ Ragauskas, M Lawoko - Green Chemistry, 2019 - pubs.rsc.org
Replacing fossil-based resources with renewable alternatives is generally acknowledged as
a critical component to address several of today's environmental concerns. In this context …

Fractionation of industrial lignins: opportunities and challenges

M Gigli, C Crestini - Green Chemistry, 2020 - pubs.rsc.org
Lignin is a readily available yet heavily underutilised resource due to its severe degree of
variability related to the plant source and to the processes employed for its isolation. Being …

Deep eutectic solvent with bifunctional Brønsted-Lewis acids for highly efficient lignocellulose fractionation

Y Bai, XF Zhang, Z Wang, T Zheng, J Yao - Bioresource Technology, 2022 - Elsevier
Green and low cost deep eutectic solvents (DESs) are promising to replace the solid acids
and ionic liquids in biomass fractionation process. To enhance the lignocellulose …

Mechanism of deep eutectic solvent delignification: insights from molecular dynamics simulations

H Xu, Y Kong, J Peng, W Wang, B Li - ACS Sustainable Chemistry …, 2021 - ACS Publications
Based on the field of ReaxFF, the pretreatment of a lignin–carbohydrate complex model in a
choline chloride-based deep eutectic solvent was proposed. The results showed that the β …

Profiling of the formation of lignin-derived monomers and dimers from Eucalyptus alkali lignin

C Zhao, Z Hu, L Shi, C Wang, F Yue, S Li, H Zhang… - Green …, 2020 - pubs.rsc.org
Lignin is a renewable and the most abundant aromatic source that can be used for extensive
chemicals and materials. Although approximately 50 million tons of lignin are produced …

Molecular understanding of the morphology and properties of lignin nanoparticles: unravelling the potential for tailored applications

IV Pylypchuk, M Karlsson, PA Lindén, ME Lindström… - Green …, 2023 - pubs.rsc.org
Studies have shown that the size of LNP depends on the molecular weight (Mw) of lignin.
There is however need for deeper understanding on the role of molecular structure on LNP …

AqSO biorefinery: A green and parameter-controlled process for the production of lignin–carbohydrate hybrid materials

D Tarasov, P Schlee, A Pranovich, A Moreno… - Green …, 2022 - pubs.rsc.org
The current biorefineries are focused on the comprehensive fractionation of biomass
components into separate lignin and carbohydrate fractions for the production of materials …