Visible light-induced organophotoredox-catalyzed difunctionalization of alkenes and alkynes

S Gupta, A Kundu, S Ghosh, A Chakraborty… - Green Chemistry, 2023 - pubs.rsc.org
In the era of organic synthesis, the direct difunctionalization strategies of alkenes and
alkynes are very eminent, which open up an excellent route to introduce two functional …

Recent advances in visible-light-mediated organic transformations in water

K Sun, QY Lv, XL Chen, LB Qu, B Yu - Green Chemistry, 2021 - pubs.rsc.org
Water, as a green reaction medium, is safe, non-toxic, and rich in reserves on Earth, while
visible light represents a renewable, clean, and abundant energy source. Organic …

Synthesis and applications of thiosulfonates and selenosulfonates as free-radical reagents

X Wang, J Meng, D Zhao, S Tang, K Sun - Chinese Chemical Letters, 2023 - Elsevier
Chalcogenative sulfones (thiosulfonates and selenosulfonates), as reactants for organic
transformations, are widely used and interesting because of their potential to react with …

Three-Component Photochemical 1, 2, 5-Trifunctionalizations of Alkenes toward Densely Functionalized Lynchpins

F Paulus, C Stein, C Heusel, TJ Stoffels… - Journal of the …, 2023 - ACS Publications
Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …

Advances in photocatalytic organic synthetic transformations in water and aqueous media

S Barata-Vallejo, DE Yerien… - … Sustainable Chemistry & …, 2021 - ACS Publications
Advances in visible light-photocatalyzed preparative synthetic organic transformations in
water or aqueous media are studied. Both the convenience of visible light photocatalytic …

Visible-light-promoted trifluoromethylthiolation and trifluoromethylselenolation of 1, 4-dihydropyridines

X Shan, X Wang, E Chen, J Liu, K Lu… - The Journal of Organic …, 2022 - ACS Publications
We report a metal-free trifluoromethylthiolation and trifluoromethylselenolation of 1, 4-
dihydropyridines with S-(trifluoromethyl) 4-methylbenzenesulfonothioate and Se …

Deacylative Thiolation by Redox‐Neutral Aromatization‐Driven C− C Fragmentation of Ketones

X Zhou, D Pyle, Z Zhang, G Dong - … Chemie International Edition, 2023 - Wiley Online Library
Herein we report the development of deacylative thiolation of diverse methyl ketones. The
reaction is redox‐neutral, and heavy‐metal‐free, which provides a new way to introduce …

Recent advances in photo-induced organic synthesis in water

Q Dou, H Zeng - Current Opinion in Green and Sustainable Chemistry, 2023 - Elsevier
The application of water in chemical synthesis has been a hot research field in green and
sustainable chemistry. With the development of photochemical synthesis, photocatalysis in …

Radical 1,5-Chloropentafluorosulfanylation of Unactivated Vinylcyclopropanes and Transformation into α-SF5 Ketones

FF Feng, JA Ma, D Cahard - The Journal of Organic Chemistry, 2021 - ACS Publications
The radical 1, 5-chloropentafluorosulfanylation of vinyl cyclopropanes (VCPs) initiated by
Et3B/O2 affords allylic pentafluorosulfanyl/homoallylic chloride products through the ring …

Ruthenium-Catalyzed Difunctionalization of Vinyl Cyclopropanes for Double m-C(sp2)–H/C-5(sp3)–H Functionalization

YY Luan, JY Li, WY Shi, Z Zhang, RQ Jiao… - Organic …, 2024 - ACS Publications
With in-depth research on 1, 2-difunctionalization, remote difunctionalization has garnered
widespread attention for achieving multifunctionality. Herein, we report a strategy for …