Playing construction with the monomer toy box for the synthesis of multi‐stimuli responsive copolymers by reversible deactivation radical polymerization protocols

F D'Acunzo, G Masci - Journal of Polymer Science, 2021 - Wiley Online Library
In this review article, we survey the 2016–June 2021 scientific literature on the synthesis of
multi‐stimuli responsive (MSR) polymers, the main focus being on reversible deactivation …

Reversible-addition fragmentation chain transfer (RAFT) mediated depolymerization of brush polymers

MJ Flanders, WM Gramlich - Polymer Chemistry, 2018 - pubs.rsc.org
Brush polymers synthesized by reversible-addition fragmentation chain transfer (RAFT)
polymerization underwent depolymerization when heated in the absence of initiator. The …

Thermoresponsive P (HEMA-co-OEGMA) copolymers: Synthesis, characteristics and solution behavior

M Kasprów, J Machnik, Ł Otulakowski, A Dworak… - RSC …, 2019 - pubs.rsc.org
Random, thermoresponsive copolymers of 2-hydroxyethyl methacrylate (HEMA) and oligo
(ethylene glycol) methyl ether methacrylate Mn= 300 (OEGMA) were synthesized via atom …

Temperature responsive polymer-supported TEMPO: An efficient and recoverable catalyst for the selective oxidation of alcohols

T Chen, Z Xu, L Zhou, L Hua, S Zhang, J Wang - Tetrahedron Letters, 2019 - Elsevier
This study aimed to combine the advantages of homogeneous catalysis and heterogeneous
catalysis by immobilizing TEMPO into a water-soluble temperature responsive polymer. The …

Synthesis and thermoresponsive properties of polymethacrylate molecular brushes with oligo(ethylene glycol)-block-oligo(propylene glycol) side chains

DM Kamorin, AS Simagin, DV Orekhov, OA Kazantsev… - Polymer Bulletin, 2021 - Springer
The synthesis and solution properties of thermoresponsive polymer molecular brushes
based on five novel diblock macromonomers (methoxy [oligo (ethylene glycol) e-block-oligo …

Multifunctional hyperbranched prepolymers with tailored degree of methylation and methacrylation

N Neumann, S Thinius, G Abels, A Hartwig, K Koschek… - Polymer, 2023 - Elsevier
A synthesis approach for multifunctional crosslinkable hyperbranched prepolymers with
tailored degree of methylation and methacrylation with full conversion of all hydroxyl groups …

Tailoring Amphiphilic Copolymers for Improved Aqueous Foam Stability

LC Brown, KM Hinnant, GC Daniels, PE Sudol… - Langmuir, 2023 - ACS Publications
Amphiphilic copolymers of various-molecular-weight (MW) poly (ethylene glycol)(PEG) were
synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization. The …

2‐(Hydroxyimino) aldehydes: Photo‐and Physicochemical Properties of a Versatile Functional Group for Monomer Design

P Gentili, M Nardi, I Antignano… - … A European Journal, 2018 - Wiley Online Library
In the context of our research on stimuli‐responsive polymers bearing the 2‐(hydroxyimino)
aldehyde (HIA) group, we have explored the photochemical behavior and physicochemical …

Synthesis of a branched star copolymer by aqueous SET-LRP and its thermo-stimuli response

L Wang, W Ding, K Song, C Dong… - … Science, Part A, 2020 - Taylor & Francis
Thermally responsive star-shaped polyacrylamides have been efficiently synthesized by
copolymerization of acrylamide (AM) with AM-based macromonomer (MPAD) by single …

Click‐Connected 2‐(Hydroxyimino) aldehydes for the Design of UV‐Responsive Functional Molecules

F D'Acunzo, L Carbonaro, AD Cort… - European Journal of …, 2021 - Wiley Online Library
Click chemistry is used to functionalize simple lipophilic and water‐soluble molecules, a
complex PEGylated phospholipid (DSPE‐PEG2000), and two benzylic substrates with the 2 …