O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Oxygen switching of the epitaxial graphene–metal interaction

R Larciprete, S Ulstrup, P Lacovig, M Dalmiglio… - ACS …, 2012 - ACS Publications
Using photoemission spectroscopy techniques, we show that oxygen intercalation is
achieved on an extended layer of epitaxial graphene on Ir (111), which results in the “lifting” …

Atomic and molecular adsorption on Ir (111)

WP Krekelberg, J Greeley… - The Journal of Physical …, 2004 - ACS Publications
The chemisorption of atomic (H, O, N, S, C), molecular (N2, CO, NO, NH3), and radical (CH3,
OH, NOH) species on Ir (111) has been systematically studied. Self-consistent, periodic …

Effect of preparation on the surface and electrocatalytic properties of RuO2+ IrO2 mixed oxide electrodes

C Angelinetta, S Trasatti, LD Atanasoska… - Materials chemistry and …, 1989 - Elsevier
RuO 2+ IrO 2 electrodes of various compositions from 0 to 100% RuO 2 have been prepared
by thermal decomposition of RuCl 3+ IrCl 3 in isopropanol solutions. The surface and …

Adsorption of N2, O2, N2O and NO on Ir (111) by EELS and TPD

JCL Cornish, NR Avery - Surface Science, 1990 - Elsevier
Adsorption of N2, O2, N2O and NO on a clean Ir (111) surface at 84 K has been studied by
high resolution EELS and TPD. N2, O2 and N2O desorb reversibly with the desorption peak …

XPS and AES study of mixed layers of RuO2 and IrO2

L Atanasoska, R Atanasoski, S Trasatti - Vacuum, 1990 - Elsevier
The surface composition of RuO 2+ IrO 2 mixed oxide layers (1–2 μm thick) deposited on
titanium by thermal degradation of the corresponding chlorides in aqueous or isopropanol …

Configurational correlations in the coverage dependent adsorption energies of oxygen atoms on late transition metal fcc (111) surfaces

SD Miller, N İnoğlu, JR Kitchin - The Journal of chemical physics, 2011 - pubs.aip.org
The coverage dependence of oxygen adsorption energies on the fcc (111) surfaces of seven
different transition metals (Rh, Ir, Pd, Pt, Cu, Au, and Ag) is demonstrated through density …

Revisiting oxygen adsorption on Ir (100)

X Cao, C Liu, T Zhang, Q Xu, D Zhang… - The Journal of …, 2022 - ACS Publications
The adsorption and dissociation of O2 on Ir (100) has been studied with X-ray photoelectron
spectroscopy (XPS), low energy electron diffraction (LEED) and scanning tunneling …

Oxidation of Ir (111): From O− Ir− O Trilayer to Bulk Oxide Formation

YB He, A Stierle, WX Li, A Farkas… - The Journal of …, 2008 - ACS Publications
The oxidation of the Ir (111) surface was studied by in situ surface X-ray diffraction (SXRD) in
an oxygen pressure range of 10− 6− 100 mbar at temperatures from 575 to 875 K, in …

Charge transfer and spillover phenomena in ceria-supported iridium catalysts: A model study

Y Lykhach, J Kubát, A Neitzel, N Tsud… - The Journal of …, 2019 - pubs.aip.org
Iridium-based materials are among the most active bifunctional catalysts in heterogeneous
catalysis and electrocatalysis. We have investigated the properties of atomically defined …