Self-assembled nanoreactors

DM Vriezema, M Comellas Aragonès… - Chemical …, 2005 - ACS Publications
In nature, chemical conversions take place in a confined environment and are closely
geared to each other such that the product of one reaction is the substrate or catalyst of the …

Predetermined chirality at metal centers

U Knof, A von Zelewsky - Angewandte Chemie International …, 1999 - Wiley Online Library
Asymmetric synthesis in coordination chemistry was described very clearly by Smirnoff in
1920, but, contrary to the development in organic chemistry, it was almost completely …

Enantiomeric MOF crystals using helical channels as palettes with bright white circularly polarized luminescence

C Zhang, ZP Yan, XY Dong, Z Han, S Li, T Fu… - Advanced …, 2020 - Wiley Online Library
The host–guest chemistry of metal–organic frameworks (MOFs) has enabled the derivation
of numerous new functionalities. However, intrinsically chiral MOFs (CMOFs) with helical …

Flipping the light switch 'ON'–the design of sensor molecules that show cation-induced fluorescence enhancement with heavy and transition metal ions

K Rurack - Spectrochimica Acta Part A: Molecular and …, 2001 - Elsevier
Real-time and real-space analysis of heavy and transition metal ions employing fluorescent
sensor molecules has received much attention over the past few years. Since many of these …

Stereospecific Alkane Hydroxylation with H2O2 Catalyzed by an Iron(II)−Tris(2-pyridylmethyl)amine Complex

C Kim, K Chen, J Kim, L Que - Journal of the American Chemical …, 1997 - ACS Publications
The stereospecific functionalization of aliphatic CH bonds is an important goal for chemistry
and biochemistry. 1 While such transformations can be carried out by organic peroxides in a …

Circular dichroism sensing: Strategies and applications

JSSK Formen, JR Howard, EV Anslyn… - Angewandte Chemie …, 2024 - Wiley Online Library
The analysis of the absolute configuration, enantiomeric composition, and concentration of
chiral compounds are frequently encountered tasks across the chemical and health …

C3 Symmetry in Asymmetric Catalysis and Chiral Recognition

C Moberg - Angewandte Chemie International Edition, 1998 - Wiley Online Library
C3 Symmetry is fascinating not only in the visual arts, as this pic- ture by MC Escher demonstra-
tes (Copyright© Cordon Ar Page 1 C3 Symmetry is fascinating not only in the visual arts, as this …

Redox-triggered chiroptical molecular switches

JW Canary - Chemical Society Reviews, 2009 - pubs.rsc.org
Efficient chiroptical molecular redox switches have been engineered that display multiple
stable optically active forms, chemically reversible redox processes, and highly sensitive …

Face-Sharing Heterotrinuclear MII−LnIII−MII (M = Mn, Fe, Co, Zn; Ln = La, Gd, Tb, Dy) Complexes: Synthesis, Structures, and Magnetic Properties

T Yamaguchi, JP Costes, Y Kishima, M Kojima… - Inorganic …, 2010 - ACS Publications
Trinuclear linear 3d− 4f− 3d complexes (3d= MnII, FeII, CoII, ZnII and 4f= LaIII, GdIII, TbIII,
DyIII) were prepared by using a tripodal nonadentate Schiff base ligand, N, N′, N′′-tris …

Formation of artificial receptors by metal-templated self-assembly

B Linton, AD Hamilton - Chemical reviews, 1997 - ACS Publications
Nature provides many examples of proteins that form their substrate binding sites by
bringing together the component pieces in a process of selfassembly. The important …