Stepwise Bi–Bi Bond Formation: From a Bi-centered Radical to Bi4 Butterfly and Bi8 Cuneane-Type Clusters
J Krüger, C Wölper, S Schulz - Inorganic Chemistry, 2020 - ACS Publications
In contrast to their lighter homologues (P, As, Sb), the synthesis of polybismuthane clusters
is still restricted to classical solid-state approaches. We herein report on systematic …
is still restricted to classical solid-state approaches. We herein report on systematic …
Salts of octabismuth (2+) polycations crystallized from Lewis-acidic ionic liquids
The reaction of Bi and BiCl3 with RbCl or CsCl in the Lewis-acidic ionic liquid (IL)[BMIm] Cl·
4AlCl3 at T= 200° C yielded air-sensitive, shiny black crystals. X-ray diffraction on single …
4AlCl3 at T= 200° C yielded air-sensitive, shiny black crystals. X-ray diffraction on single …
Bismuth Polycations Revisited: Alternative Synthesis and Electronic Structure of Bi6Br7, and Bonding in Main-Group Polyatomic Ions from a Direct Space …
EA Stroganova, SI Troyanov, IV Morozov… - Crystals, 2020 - mdpi.com
A bismuth subbromide, Bi6Br7, was synthesized in the form of single crystals using the
reaction between Bi and Hg2Br2 in a gradient furnace. Its crystal structure was …
reaction between Bi and Hg2Br2 in a gradient furnace. Its crystal structure was …
Pseudohalogen chemistry in ionic liquids with non‐innocent cations and Anions
S Arlt, K Bläsing, J Harloff, KC Laatz, D Michalik… - …, 2021 - Wiley Online Library
Within the second funding period of the SPP 1708 “Material Synthesis near Room
Temperature”, which started in 2017, we were able to synthesize novel anionic species …
Temperature”, which started in 2017, we were able to synthesize novel anionic species …
Bismuth-rich bimetallic clusters (CuBi8)3+ and [MBi10]4+ (M = Pd, Pt) from ionothermal synthesis
Abstract The reaction of Bi, BiBr3, and CuBr in the Lewis-acidic ionic liquid [BMIm] Br· 4AlBr3
(BMIm= 1-n-butyl-3-limidazolium) at 180° C yielded air-sensitive, shiny black crystals of …
(BMIm= 1-n-butyl-3-limidazolium) at 180° C yielded air-sensitive, shiny black crystals of …
Hexacyanidosilicates with functionalized imidazolium counterions
J Harloff, KC Laatz, S Lerch, A Schulz… - European Journal of …, 2020 - Wiley Online Library
Functionalized imidazolium cations were combined with the hexacyanidosilicate anion,[Si
(CN) 6] 2–, by salt metathesis reactions with K2 [Si (CN) 6], yielding novel ionic compounds …
(CN) 6] 2–, by salt metathesis reactions with K2 [Si (CN) 6], yielding novel ionic compounds …
[PDF][PDF] Synthese und Charakterisierung neuer cyanidhaltiger Anionen
P Stoer - 2020 - d-nb.info
In der vorliegenden Dissertation werden die Ergebnisse der Untersuchungen zur Synthese
und Reaktivität von Salzen mit neuen pseudohalogenidhaltigen Anionen sowie deren …
und Reaktivität von Salzen mit neuen pseudohalogenidhaltigen Anionen sowie deren …