Nonplanar porphyrins: synthesis, properties, and unique functionalities

T Ishizuka, N Grover, CJ Kingsbury, H Kotani… - Chemical Society …, 2022 - pubs.rsc.org
Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …

β-Pyrrole functionalized porphyrins: Synthesis, electronic properties, and applications in sensing and DSSC

B Sekaran, R Misra - Coordination Chemistry Reviews, 2022 - Elsevier
Porphyrin is a class of tetrapyrrole compound with both natural and synthetic occurrence
and its derivatives perform a significant role as light harvesting antenna in the natural …

Push–pull octaphenylporphyrins with mixed substituents pattern: Synthesis, redox, ultrafast dynamics and nonlinear optical studies

S Kumari, I Yadav, JN Acharyya, M Shanu… - Dyes and …, 2023 - Elsevier
A new family of β-functionalized octaphenylporphyrins, MOPP (NO 2) Br 3 (M= 2H, Zn II, Ni II,
or Cu II, and OPP= octaphenylporphyrin) has been synthesized possessing unsymmetrical …

A2B2 type porphyrins with meso-donor groups: Synthesis, X-ray structures, DFT studies and photocatalytic application using sunlight

V Pandey, A Janaagal, A Jain, S Mori, I Gupta - Dyes and Pigments, 2023 - Elsevier
The trans-A 2 B 2 type porphyrins bearing thiophene linked N-butylcarbazole or N-
butylphenothiazine groups at the meso-positions were synthesized. Donor− acceptor (D− A) …

Fine-tuning metal and ligand-centered redox potentials of homoleptic bis-terpyridine complexes with 4′-aryl substituents

JC Dickenson, MKE Haley, JT Hyde, ZM Reid… - Inorganic …, 2021 - ACS Publications
Homoleptic transition-metal complexes of 2, 2': 6′, 2 ″-terpyridine (terpy) and substituted
derivatives of the form [M (R-terpy) 2] 2+ display a wide range of redox potentials that …

Facile Synthesis of β-Tetracyano Vanadyl Porphyrin from Its Tetrabromo Analogue and Its Excellent Catalytic Activity for Bromination and Epoxidation Reactions

MR Maurya, V Prakash, TA Dar, M Sankar - ACS omega, 2023 - ACS Publications
Complex 2, 3, 12, 13-tetracyano-5, 10, 15, 20-tetraphenylporphyrinatooxidovanadium
(IV){[VIVOTPP (CN) 4], 2} has been prepared by nucleophilic substitution of β-bromo groups …

Synthesis, spectral, and electrochemical studies of electronically tunable β-substituted porphyrins with mixed substituent pattern

R Kumar, M Sankar - Inorganic Chemistry, 2014 - ACS Publications
Two new families of porphyrins with mixed substituent pattern, viz. 2-nitro-12, 13-
disubstituted-meso-tetraphenylporphyrins (H2TPP (NO2) X2, X= Ph, phenylethynyl (PE), 2 …

Robust Zinc (II) porphyrin Catalyst for Visible Light Induced C–H Arylation of Heteroarenes

A Janaagal, Sanyam, A Mondal… - The Journal of Organic …, 2023 - ACS Publications
Zinc (II) porphyrin catalyzed light induced C–H arylation of heteroarenes from anilines is
discussed. The method is nontoxic and efficient, using only 0.5 mol% of porphyrin catalyst to …

Strong two-photon absorption and ultrafast dynamics of meso-functionalized “push–pull” trans-A 2 BC porphyrins

S Kumar, JN Acharyya, D Banerjee, VR Soma… - Dalton …, 2021 - pubs.rsc.org
A new series of “push–pull” meso-substituted trans-A2BC porphyrins, where A= mesityl, B=
phenothiazine (push) and C= o/p-nitrophenyl moiety (pull) and M= 2H, Ni (II), Cu (II), and Zn …

β-tetracyanobutadiene-appended porphyrins: Facile synthesis, spectral and electrochemical redox properties, and their utilization as excellent optical limiters

RK Rohal, JN Acharyya, M Shanu, GV Prakash… - Inorganic …, 2021 - ACS Publications
A series of β-TCBD (1, 1, 4, 4-tetracyano-buta-1, 3-diene)-appended porphyrins, M-TCBD
(M= 2H, Co (II), Ni (II), Cu (II), and Zn (II)), was synthesized from 2, 3-diphenylethynyl-12-nitro …