Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals

C Benelli, D Gatteschi - Chemical Reviews, 2002 - ACS Publications
Rare-earth ions are characterized by large unquenched orbital angular momentum
associated with the internal nature of the valence f orbitals. In fact, with the exception of …

The structures and magnetic properties of complexes containing 3d-and 4f-metals

REP Winpenny - Chemical Society Reviews, 1998 - pubs.rsc.org
Heterometallic complexes containing 3d-/4f-metals have been made with a variety of ligands
including Schiff-bases, pyridonates and amino-alcohols. The majority of species with Schiff …

AN23– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K

JD Rinehart, M Fang, WJ Evans… - Journal of the American …, 2011 - ACS Publications
The synthesis and magnetic properties of three new N23–radical-bridged dilanthanide
complexes,{[(Me3Si) 2N] 2 (THF) Ln} 2 (μ-η2: η2-N2)−(Ln= Tb, Ho, Er), are reported. All …

d–f Heteronuclear complexes: synthesis, structures and physicochemical aspects

M Sakamoto, K Manseki, H Ōkawa - Coordination Chemistry Reviews, 2001 - Elsevier
d–f Heteronuclear complexes: synthesis, structures and physicochemical aspects -
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …

Magnetic lanthanide–transition-metal organic–inorganic hybrid materials: From discrete clusters to extended frameworks

YG Huang, FL Jiang, MC Hong - Coordination Chemistry Reviews, 2009 - Elsevier
Magnetic lanthanide–transition-metal hybrid materials have enjoyed increasing attraction
because they not only provide examples for studying magnetic coupling involving …

Influence of Anionic Ligands (X) on the Nature and Magnetic Properties of Dinuclear LCuGdX3·nH2O Complexes (LH2 Standing for Tetradentate Schiff Base Ligands Deriving from 2-Hydroxy-3 …

JP Costes, F Dahan, A Dupuis - Inorganic chemistry, 2000 - ACS Publications
The monometallic precursor L1Cu (L1H2 standing for 1, 3-bis ((3-methoxysalicylidene)
amino)-2, 2 '-dimethylpropane) reacts with GdCl3⊙ 6H2O to afford a dinuclear complex …

Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Design and Magnetic Properties of a Magnetically Isolated GdIIICuII Pair. Crystal Structures of [Gd(hfa)3Cu(salen)], [Y(hfa)3Cu(salen)], [Gd(hfa)3Cu(salen)(Meim)], and [La(hfa)3(H2O)Cu …

I Ramade, O Kahn, Y Jeannin, F Robert - Inorganic Chemistry, 1997 - ACS Publications
The crystal structures of three compounds have been determined at room temperature,
namely [Gd (hfa) 3Cu (salen)](1),[Y (hfa) 3Cu (salen)](2), and [Gd (hfa) 3Cu …

Synthesis and Magnetic Behavior of Rare‐Earth Complexes with N,O‐Chelating Nitronyl Nitroxide Triazole Ligands: Example of a [GdIII{Organic Radical}2] Compound with an …

JP Sutter, ML Kahn, S Golhen… - … –A European Journal, 1998 - Wiley Online Library
A ferromagnetically coupled gadolinium–radical compound is described. A series of three
lanthanide complexes of general formula [Ln (organic radical) 2 (NO3) 3](Ln= Y3+, La3+ …

Systematic Study of a Family of Butterfly-Like {M2Ln2} Molecular Magnets (M = MgII, MnIII, CoII, NiII, and CuII; Ln = YIII, GdIII, TbIII, DyIII, HoIII, and ErIII)

E Moreno Pineda, NF Chilton, F Tuna… - Inorganic …, 2015 - ACS Publications
A family of 3d–4f [MII2LnIII2 (μ3-OH) 2 (O2C t Bu) 10] 2–“butterflies”(where MII= Mg, Co, Ni,
and Cu; LnIII= Y, Gd, Tb, Dy, Ho, and Er) and [MnIII2LnIII2 (μ3-O) 2 (O2C t Bu) 10] 2 …