Linear alpha olefins such as 1-hexene are widely used in the chemical industry. Over the
past 15 years there has been considerable industrial interest in the selective trimerisation of …

This article summarizes basic principles and recent progress in the field of cascade‐
branched polymers. Methods for the preparation of macromolecules with hyperbranched …

In this perspective, recent developments on palladium and nickel mediated chain walking
olefin polymerization and copolymerization with polar functionalized comonomers are …

Structurally different from existing polyethylene grades, hyperbranched polyethylenes
(HBPEs) synthesized by Pd–diimine-catalyzed chain walking polymerization represent a …

Novel amine bis (phenolate) zirconium dibenzyl complexes were synthesized in quantitative
yields from a versatile family of chelating amine− bis ((2-hydroxyaryl) methyl) ligand …

A group of polyethylenes synthesized using palladium α-diimine catalysts were studied
using 13C NMR spectroscopy, intensity light scattering, dynamic light scattering, and …

Angew. Chem. Int. Ed. 2001, 40, No. 13 WILEY-VCH Verlag GmbH, D-69451 Weinheim,
2001 1433-7851/01/4013-2517 $17.50+. 50/0 2517 phenyl group. It appears that the …

Chain‐walking catalysts are demonstrated to control the branching topology of polyethylene
by tuning the competition between monomer insertion and chain isomerization (walking) …

Early transition metal catalysts produce high-density and linear low-density polyethylenes
with spectacular efficiency. Nevertheless, these catalysts are ineffective in producing low …

The branching topology of ethylene polar copolymers was for the first time successfully
controlled by copolymerization of ethylene with polar olefins using a palladium-bisimine …