Recent Advancements in Typical Friedel–Crafts Alkylation Reactions Focused on Targeting Arene Nucleophiles

S Singh, CK Hazra - Synthesis, 2023 - thieme-connect.com
This review delves into recent advances and significant breakthroughs in the field of the
catalytic Friedel–Crafts alkylation of targeted arenes or heteroarenes. Though a few earlier …

Visible photons as ideal reagents for the activation of coloured organic compounds

L Di Terlizzi, L Nicchio, S Protti… - Chemical Society Reviews, 2024 - pubs.rsc.org
In recent decades, the traceless nature of visible photons has been exploited for the
development of efficient synthetic strategies for the photoconversion of colourless …

Organocatalytic Friedel–Crafts arylation of aldehydes with indoles utilizing N-heterocyclic iod (az) olium salts as halogen-bonding catalysts

EM Galathri, TJ Kuczmera, BJ Nachtsheim… - Green …, 2024 - pubs.rsc.org
The Friedel–Crafts arylation is among the most known organic reactions, usually being
promoted by a Lewis acid, that have been employed for the synthesis of bis-indolyl …

Synthetic methodologies and therapeutic potential of indole-3-carbinol (I3C) and its derivatives

F Centofanti, A Buono, M Verboni, C Tomino… - Pharmaceuticals, 2023 - mdpi.com
Indole-3-carbinol (I3C) is a natural product contained in vegetables belonging to the
Brassicaceae family and has been studied in recent decades for its biological and …

Visible photons for the regioselective nucleophilic ring opening of epoxides

B Bernardoni, L Di Terlizzi, EM Galathri, CG Kokotos… - Green …, 2024 - pubs.rsc.org
Arylazo sulfones were used as Photoacid Generators (PAGs) for the visible-light
photorelease of strong sulfonic acids to promote the ring opening of epoxides in benign …

Visible‐Light‐Promoted Reaction of N‐Hydroxyphthalimide Esters with Vinyl Boronic Pinacol Ester

PL Gkizis, I Triandafillidi, NA Stini… - European Journal of …, 2023 - Wiley Online Library
A novel and easy‐to‐execute light‐driven protocol for the preparation of alkyl boronic acid
pinacol esters from vinyl boronate using N‐hydroxyphthalimide esters as the potential …

Photochemical Aminochlorination of Alkenes without the Use of an External Catalyst

CT Constantinou, PL Gkizis… - … A European Journal, 2023 - Wiley Online Library
The niche field of photochemistry offers opportunities that are not found in “traditional”
ground state chemical pathways. Aminochlorinated derivatives are an interesting family of 1 …

Arylazo sulfones: multifaceted photochemical reagents and beyond

R Chawla, AK Singh, PK Dutta - Organic & Biomolecular Chemistry, 2024 - pubs.rsc.org
The photochemical action of arylazo sulfones under visible light irradiation has recently
gained considerable attention for the construction of carbon–carbon and carbon …

UVA‐Light‐Promoted Catalyst‐Free Photochemical Aerobic Oxidation of Boronic Acids

PL Gkizis, CT Constantinou… - European Journal of …, 2023 - Wiley Online Library
The hydroxy group, and the phenol moiety in particular, is ubiquitous in several natural
products, in organic synthesis and/or pharmaceutical industry. With the uprise of photoredox …

Unlocking diversity: from simple to cutting-edge synthetic methodologies of bis (indolyl) methanes

P Teli, S Soni, S Teli, S Agarwal - Topics in Current Chemistry, 2024 - Springer
From a synthetic perspective, bis (indolyl) methanes have undergone extensive
investigation over the past two to three decades owing to their remarkable pharmacological …