Cation− π interactions in organic synthesis

S Yamada - Chemical reviews, 2018 - ACS Publications
The cation− π interaction is an attractive noncovalent interaction between a cation and a π
system. Due to the stronger interaction energy than those of the other π interactions, such as …

Recent advances in the development of aryl-based foldamers

I Saraogi, AD Hamilton - Chemical Society Reviews, 2009 - pubs.rsc.org
In recent years, significant effort has gone into making synthetic oligomers that can attain
well-defined conformations analogous to the folding of biomolecules. The diversity of the …

Rethinking the term “pi-stacking”

CR Martinez, BL Iverson - Chemical Science, 2012 - pubs.rsc.org
It has become common to reference “pi-stacking” forces or “pi–pi interactions” when
describing the interactions between neighbouring aromatic rings. Here, we review …

Strong and reversible binding of carbon dioxide in a green metal–organic framework

JJ Gassensmith, H Furukawa… - Journal of the …, 2011 - ACS Publications
The efficient capture and storage of gaseous CO2 is a pressing environmental problem.
Although porous metal–organic frameworks (MOFs) have been shown to be very effective at …

Dynamic foldamer chemistry

BAF Le Bailly, J Clayden - Chemical Communications, 2016 - pubs.rsc.org
Foldamers can be made more than pieces of static, conformationally uniform molecular
architecture by designing into their structure the conformational dynamism characteristic of …

Pyridine/Oxadiazole‐Based Helical Foldamer Ion Channels with Exceptionally High K+/Na+ Selectivity

F Chen, J Shen, N Li, A Roy, R Ye… - Angewandte Chemie …, 2020 - Wiley Online Library
Protein channels are characterized by high transport selectivity, which is essential for
maintaining cellular function. Efforts to reproduce such high selectivity over the past four …

Hierarchical helices of helices directed by Pt⋯ Pt and π–π stacking interactions: reciprocal association of multiple helices of dinuclear alkynylplatinum (II) complex with …

SYL Leung, VWW Yam - Chemical Science, 2013 - pubs.rsc.org
A dinuclear alkynylplatinum (II) terpyridine complex containing an amphiphilic binaphthol
bridge was designed and synthesized, and was shown to display cylindrical columnar …

Reversible dispersion and release of carbon nanotubes using foldable oligomers

Z Zhang, Y Che, RA Smaldone, M Xu… - Journal of the …, 2010 - ACS Publications
Foldamers are synthetic and designable oligomers that adopt a conformationally ordered
state in selected solvents. We found that oligo (m-phenylene ethynylene) s, which are single …

Oxidation at the core–ligand interface of Au lipoic acid nanoclusters that enhances the near-IR luminescence

J Jiang, CV Conroy, MM Kvetny, GJ Lake… - The Journal of …, 2014 - ACS Publications
A new surface oxidation mechanism that enhances the luminescence of Au nanoclusters is
discovered in Au nanoclusters synthesized with disulfide lipoic acid. The quantum efficiency …

Synthesis, structural investigations, hydrogen− deuterium exchange studies, and molecular modeling of conformationally stablilized aromatic oligoamides

Y Yan, B Qin, C Ren, X Chen, YK Yip… - Journal of the …, 2010 - ACS Publications
Biasing the conformational preferences of aromatic oligoamides by internally placing
intramolecular hydrogen bonds has led to a series of stably folded molecular strands. This …