This review highlights the preparation of sodium sulfinates (RSO2Na) and their multifaceted
synthetic applications. Substantial progress has been made over the last decade in the …

Abstract gem‐Difluorocyclopropanes (F2CPs) have aroused considerable attention not only
from the structural perspective but also due to their ability to participate in various valuable …

An unprecedented Pd‐catalyzed fluorinative bifunctionalization of aziridines and azetidines
was successfully developed via regioselective C− C and C− F bond cleavage of gem …

Arylsulfonyl compounds are among the most important compounds in pharmaceutical and
medicinal chemistry. Hence, a wide variety of sulfonylation methods have been reported …

Developing new strategies to enable chemo-and regioselective reductions is an important
topic in chemical research. Herein, an efficient and regioselective Pd/IPrBIDEA-catalyzed …

The unique properties of the fluorine-containing compounds and their widespread
applications raise the demand for dependable synthetic methods on the precise introduction …

Defluorinative manipulation of polyfluorinated molecules has shown great promise due to its
granting of synthetic versatility to inert C− F bonds. The development of chemo‐, stereo‐and …

Controlling the selectivity of synthetically useful reactions has been a longstanding objective
of organic chemistry. We report a regiodivergent synthetic protocol allowing access to …

Conventional approaches for Pd‐catalyzed ring‐opening cross‐couplings of gem‐
difluorocyclopropanes with nucleophiles predominantly deliver the β‐fluoroalkene scaffolds …

Palladium-catalyzed synthesis of 3-acyl and-allyl indoles has been realized by merging
nucleophilic cyclization of ortho-alkynylanilines with ring opening of three-membered rings …