Heterometallic cages: synthesis and applications

LK Moree, LAV Faulkner, JD Crowley - Chemical Society Reviews, 2024 - pubs.rsc.org
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Better Together: Functional Heterobimetallic Macrocyclic and Cage‐like Assemblies

M Hardy, A Lützen - Chemistry–A European Journal, 2020 - Wiley Online Library
Metallosupramolecular chemistry has attracted the interest of generations of researches due
to the versatile properties and functionalities of oligonuclear coordination complexes. Quite …

A Family of Heterobimetallic Cubes Shows Spin‐Crossover Behaviour Near Room Temperature

M Hardy, J Tessarolo, JJ Holstein… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract Using 4‐(4′‐pyridyl) aniline as a simple organic building block in combination with
three different aldehyde components together with metal (II) salts gave three different Fe8Pt6 …

Dynamic Complex‐to‐Complex Transformations of Heterobimetallic Systems Influence the Cage Structure or Spin State of Iron (II) Ions

M Hardy, N Struch, JJ Holstein… - Angewandte Chemie …, 2020 - Wiley Online Library
Two new heterobimetallic cages, a trigonal‐bipyramidal and a cubic one, were assembled
from the same mononuclear metalloligand by adopting the molecular library approach …

Enantiopure trigonal bipyramidal coordination cages templated by in situ self-organized D2h-symmetric anions

S Guo, WW Zhan, FL Yang, J Zhou, YH Duan… - Nature …, 2024 - nature.com
The control of a molecule's geometry, chirality, and physical properties has long been a
challenging pursuit. Our study introduces a dependable method for assembling D 3 …

Metalloligand strategies for assembling heteronuclear nanocages–recent developments

F Li, LF Lindoy - Australian Journal of Chemistry, 2019 - CSIRO Publishing
The use of metalloligands as building blocks for the assembly of metallo-organic cages has
received increasing attention over the past two decades or so. In part, the popularity of this …

Complementarity and Preorganisation in the Assembly of Heterometallic–Organic Cages via the Metalloligand Approach—Recent Advances

F Li, LF Lindoy - Chemistry, 2022 - mdpi.com
The design of new metallocage polyhedra towards pre-determined structures can offer both
practical as well as intellectual challenges. In this mini-review we discuss a selection of …

Stepwise synthesis of heterotrimetallic Fe II/Pd II/Au I coordination cages

N Eren, F Fadaei-Tirani, K Severin - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
The synthesis of heterotrimetallic molecular cages is reported. The assemblies contain three
types of coordination compounds: FeII clathrochelate complexes, AuI3 (pyrazolate) 3 …

A family of diastereomeric dodecanuclear coordination cages based on inversion of chirality of individual triangular cyclic helicate faces

SP Argent, FC Jackson, HM Chan, S Meyrick… - Chemical …, 2020 - pubs.rsc.org
The dodecanuclear coordination cage [Cd12 (Lnaph) 12 (Lmes) 4](BF4) 24 consists of a set
of four triangular, trinuclear helical panels {Cd3 (μ-Lnaph) 3} 6+(based on ditopic bridging …

Spontaneous Resolution and Structure Transformation of NiII Metal–Organic Frameworks from an Achiral Precursor

Y Tao, C Yang, H Fang, HD Bian, X Xu… - Crystal Growth & …, 2019 - ACS Publications
Metal-center-driven spontaneous resolution of a pair of chiral doubly interpenetrated metal–
organic frameworks (MOFs),[Ni3 (ptd) 6]· 15.5 H2O (1), which was synthesized from achiral …