Vapochromic effect in switchable molecular-based spin crossover compounds

E Resines-Urien, E Fernandez-Bartolome… - Chemical Society …, 2023 - pubs.rsc.org
Coordination complexes based on transition metal ions displaying [Ar] 3d4–3d7 electronic
configurations can undergo the likely most spectacular switchable phenomena found in …

[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

Structure: function relationships in molecular spin-crossover complexes

MA Halcrow - Chemical Society Reviews, 2011 - pubs.rsc.org
Spin-crossover compounds are becoming increasingly popular for device and sensor
applications, and in soft materials, that make use of their switchable colour, paramagnetism …

Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state

C Lochenie, K Schötz, F Panzer, H Kurz… - Journal of the …, 2018 - ACS Publications
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …

Iron (II) complexes of 2, 6-di (pyrazol-1-yl) pyridines—A versatile system for spin-crossover research

MA Halcrow - Coordination Chemistry Reviews, 2009 - Elsevier
Synthetic procedures are available for the derivatisation of almost every position of the 2, 6-
di (pyrazol-1-yl) pyridine (1-bpp) skeleton. This has led to the preparation of a large number …

An iron (II) spin-crossover complex with a 70 K wide thermal hysteresis loop

B Weber, W Bauer, J Obel - Angewandte Chemie International …, 2008 - eref.uni-bayreuth.de
Going loopy: A new iron (II) spin-crossover complex displays a 70 K wide thermal hysteresis
loop, which can be explained by an intermolecular 2D network of hydrogen bonds. This is …

Spin crossover complexes with N4O2 coordination sphere—The influence of covalent linkers on cooperative interactions

B Weber - Coordination Chemistry Reviews, 2009 - Elsevier
About 10 years ago Jäger and co-workers demonstrated the possibility of preparing an iron
(II) spin crossover complex of a Schiff-base like N2O2 coordinating ligand in combination …

Spin-crossover in iron (II)-Schiff base complexes

KS Kumar, Y Bayeh, T Gebretsadik, F Elemo… - Dalton …, 2019 - pubs.rsc.org
The spin-crossover (SCO) phenomenon is one of the most prominent examples of bi-stability
in molecular chemistry, and the SCO complexes are proposed for nanotechnological …

Spin crossover–quo vadis?

P Gütlich - European Journal of Inorganic Chemistry, 2013 - Wiley Online Library
This retrospective essay is an attempt to span the bridge over eight decades of research on
spin crossover (SCO), one of the most fascinating dynamic electron structure phenomena of …

Structural Insights into Hysteretic Spin‐Crossover in a Set of Iron(II)‐2,6‐bis(1H‐Pyrazol‐1‐yl)Pyridine) Complexes

N Suryadevara, A Mizuno, L Spieker… - … A European Journal, 2022 - Wiley Online Library
Bistable spin‐crossover (SCO) complexes that undergo abrupt and hysteretic (ΔT1/2) spin‐
state switching are desirable for molecule‐based switching and memory applications. In this …