Toward the rational design of novel noncentrosymmetric materials: Factors influencing the framework structures

KM Ok - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Solid-state materials with extended structures have revealed many interesting
structure-related characteristics. Among many, materials crystallizing in noncentrosymmetric …

A survey of stereoactive oxysalts for linear and nonlinear optical applications

PF Li, JG Mao, F Kong - Materials Today Physics, 2023 - Elsevier
Stereoactive oxysalts can exhibit excellent nonlinear optical coefficients and linear optical
properties, like large birefringence and strong second harmonic generation (SHG) intensity …

Y 2 (Te 4 O 10)(SO 4): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

PF Li, CL Hu, F Kong, SM Ying, JG Mao - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
Two new yttrium sulfate tellurites, namely, Y3 (TeO3) 2 (SO4) 2 (OH)(H2O) and Y2
(Te4O10)(SO4), were achieved in our exploration of new sulfate tellurites, with a large …

Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra

Y Yang, Y Guo, B Zhang, T Wang, YG Chen… - Inorganic …, 2022 - ACS Publications
The exploration of nonlinear-/linear-optical crystal materials with high performance is an
extremely difficult research project. Herein, the two new lead tellurite crystals BaPbTe2O6 …

β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

S Han, C Huang, A Tudi, S Hu… - Chemistry–A European …, 2019 - Wiley Online Library
The first triple‐layered borate with edge‐sharing BO4 tetrahedra, β‐CsB9O14 was obtained
under vacuum‐sealed condition. It represents a new structure type and enriches the …

MII2M3IIIF3 (Te6F2O16)(MII= Pb, Ba; MIII= Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings

PF Li, F Kong, JG Mao - Journal of Solid State Chemistry, 2020 - Elsevier
Three new isostructural mixed anionic tellurites, namely, Pb 2 Al 3 F 3 (Te 6 F 2 O 16)(1), Pb
2 Ga 3 F 3 (Te 6 F 2 O 16)(2) and Ba 2 Ga 3 F 3 (Te 6 F 2 O 16)(3), have been synthesized …

Noncentrosymmetric Tellurite Halides Created by Depolymerization Strategy: Toward Strong SHG Intensity and Wide Bandgap

DD Zhou, CL Hu, XW Zhang, JG Mao, F Kong - Chemical Science, 2024 - pubs.rsc.org
Design and synthesis of nonlinear optical (NLO) materials with strong second harmonic
generation (SHG) effect and wide band gap is a long-standing challenge because of their …

Tuning of nonlinear optical and ferroelectric properties via the cationic composition of Ca9. 5–1.5 xBixCd (VO4) 7 solid solutions

NG Dorbakov, OV Baryshnikova, VA Morozov… - Materials & Design, 2017 - Elsevier
Abstract Ca 9.5–1.5x Bi x Cd (VO 4) 7 (0≤ x≤ 1) solid solutions with the whitlockite-type
structure (SG R3c) were synthesized by a standard solid-state method in air. Structures of …

A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge

S Han, Y Wang, B Zhang, Z Yang, S Pan - Inorganic Chemistry, 2018 - ACS Publications
A new member of fluorooxoborates, Li2Na0. 9K0. 1B5O8F2, was obtained in the sealed
system, and single-crystal X-ray diffraction was used to determine its structure. It contains a …

Enhanced nonlinear optical activity and Ca2+-conductivity in Са10. 5-xPbx (VO4) 7 ferroelectrics

SY Stefanovich, DA Petrova, VA Morozov… - Journal of Alloys and …, 2018 - Elsevier
Abstract Са 3 (VO 4) 2-based compositions are considered as promising multifunctional
materials combining ferroelectric, optical nonlinear, and Ca 2+-ion conductive properties …