Excited-state proton coupled charge transfer modulated by molecular structure and media polarization

AP Demchenko, KC Tang, PT Chou - Chemical Society Reviews, 2013 - pubs.rsc.org
Charge and proton transfer reactions in the excited states of organic dyes can be coupled in
many different ways. Despite the complementarity of charges, they can occur on different …

[HTML][HTML] Thermodynamic vs. kinetic control of excited-state proton transfer reactions

VI Tomin, AP Demchenko, PT Chou - Journal of Photochemistry and …, 2015 - Elsevier
Abstract The “Excited-State Intramolecular Proton Transfer”(ESIPT) reactions in a number of
organic fluorophores are among the fastest basic chemical reactions known so far and their …

Fluorescent probes based on charge and proton transfer for probing biomolecular environment

VG Pivovarenko, AS Klymchenko - The Chemical Record, 2024 - Wiley Online Library
Fluorescent probes for sensing fundamental properties of biomolecular environment, such
as polarity and hydration, help to study assembly of lipids into biomembranes, sensing …

The relationship between solid-state fluorescence intensity and molecular packing of coumarin dyes

SY Park, M Ebihara, Y Kubota, K Funabiki, M Matsui - Dyes and Pigments, 2009 - Elsevier
The solid-state fluorescence intensity of coumarin dyes depends on the substituents present
at the 4-and 7-positions. 7-(Diethylamino) coumarins showed higher solid-state …

Excited state intramolecular proton transfer of 2-phenyl, 3-hydroxybenzo [g] quinolones in solution and in G4 supramolecular hydrogels

S Dutta, D Mandal - Journal of Molecular Liquids, 2022 - Elsevier
Abstract The 2-Phenyl, 3-Hydroxybenzo [g] quinolone (2P3HBQ) fluorophore and its
derivative, 2-(4′-hydroxyphenyl)-3-hydroxybenzo [g] quinolone (2HP3HBQ), exhibit well …

[HTML][HTML] Visualization and sensing of intermolecular interactions with two-color fluorescent probes

AP Demchenko - FEBS letters, 2006 - Elsevier
We developed a new generic fluorescence sensing technology based on the change of
relative intensities between two well-separated emission bands of the novel functional 3 …

Practical aspects of wavelength ratiometry in the studies of intermolecular interactions

AP Demchenko - Journal of Molecular Structure, 2014 - Elsevier
Wavelength ratiometry (often abbreviated as λ-ratiometry) is one of the most popular
methods to study intermolecular interactions that allows obtaining both thermodynamic and …

Phosphine-Mediated Redox Cyclization of 1-(2-Nitroaryl) prop-2-ynones to 3-Hydroxyquinolin-4-ones: Formal Intramolecular Oxyamination of α, β-Ynones

L Dutta, SSV Ramasastry - Organic Letters, 2022 - ACS Publications
3-Hydroxyquinoline-4 (1 H)-ones (3HQs) are privileged structural motifs. The current
methods for their synthesis necessitate strongly acidic or basic conditions, which hamper the …

Synthesis of Aza‐Rocaglates via ESIPT‐Mediated (3+2) Photocycloaddition

W Wang, R Cencic, L Whitesell… - … A European Journal, 2016 - Wiley Online Library
Synthesis of aza‐rocaglates, nitrogen‐containing analogues of the rocaglate natural
products, is reported. The route features ESIPT‐mediated (3+ 2) photocycloaddition of 1 …

Modulation of excited-state intramolecular proton transfer by viscosity in protic media

DA Yushchenko, VV Shvadchak… - The Journal of …, 2007 - ACS Publications
3-Hydroxyquinolones undergo excited-state intramolecular proton transfer (ESIPT), resulting
in a dual emission highly sensitive to H-bonding perturbations. Here, we report on the strong …