3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Nitrene transfer catalysts for enantioselective C–N bond formation

M Ju, JM Schomaker - Nature Reviews Chemistry, 2021 - nature.com
Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

Manganese-Catalyzed Oxidative Azidation of C(sp3)–H Bonds under Electrophotocatalytic Conditions

L Niu, C Jiang, Y Liang, D Liu, F Bu, R Shi… - Journal of the …, 2020 - ACS Publications
The selective installation of azide groups into C (sp3)–H bonds is a priority research topic in
organic synthesis, particularly in pharmaceutical discovery and late-stage diversification …

Transition metal-catalyzed C–H amination: scope, mechanism, and applications

Y Park, Y Kim, S Chang - Chemical reviews, 2017 - ACS Publications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

C–H amination via electrophotocatalytic ritter-type reaction

T Shen, TH Lambert - Journal of the American Chemical Society, 2021 - ACS Publications
A method for C–H bond amination via an electrophotocatalytic Ritter-type reaction is
described. The reaction is catalyzed by a trisaminocyclopropenium (TAC) ion in an …

Transition-metal-catalyzed C–N bond forming reactions using organic azides as the nitrogen source: a journey for the mild and versatile C–H amination

K Shin, H Kim, S Chang - Accounts of chemical research, 2015 - ACS Publications
Conspectus Owing to the prevalence of nitrogen-containing compounds in functional
materials, natural products and important pharmaceutical agents, chemists have actively …

C H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

J Yamaguchi, AD Yamaguchi… - Angewandte Chemie …, 2012 - Wiley Online Library
The direct functionalization of C H bonds in organic compounds has recently emerged as a
powerful and ideal method for the formation of carbon–carbon and carbon–heteroatom …

Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations

R Trammell, K Rajabimoghadam… - Chemical …, 2019 - ACS Publications
Copper is one of the most abundant and less toxic transition metals. Nature takes advantage
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …

Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C–H bonds

JL Roizen, ME Harvey, J Du Bois - Accounts of chemical research, 2012 - ACS Publications
For more than a century, chemists have endeavored to discover and develop reaction
processes that enable the selective oxidation of hydrocarbons. In the 1970s, Abramovitch …

Toward renewable amines: recent advances in the catalytic amination of biomass-derived oxygenates

NK Gupta, P Reif, P Palenicek, M Rose - ACS Catalysis, 2022 - ACS Publications
Synthesis of high-value-added chemicals from biomass and/or biomass-derived platform
molecules is considered an important strategy to mitigate the global dependency on fossil …