Probing and manipulating noncovalent interactions in functional polymeric systems

J Chen, Q Peng, X Peng, H Zhang, H Zeng - Chemical Reviews, 2022 - ACS Publications
Noncovalent interactions, which usually feature tunable strength, reversibility, and
environmental adaptability, have been recognized as driving forces in a variety of biological …

Solvent nanostructure, the solvophobic effect and amphiphile self-assembly in ionic liquids

TL Greaves, CJ Drummond - Chemical Society Reviews, 2013 - pubs.rsc.org
The ability of ionic liquids (ILs) to support amphiphile self-assembly into a range of
mesophase structures has been established as a widespread phenomenon. From the ILs …

Weakly hydrated anions bind to polymers but not monomers in aqueous solutions

BA Rogers, HI Okur, C Yan, T Yang, J Heyda… - Nature Chemistry, 2022 - nature.com
Weakly hydrated anions help to solubilize hydrophobic macromolecules in aqueous
solutions, but small molecules comprising the same chemical constituents precipitate out …

Water structural transformation at molecular hydrophobic interfaces

JG Davis, KP Gierszal, P Wang, D Ben-Amotz - Nature, 2012 - nature.com
Hydrophobic hydration is considered to have a key role in biological processes ranging from
membrane formation to protein folding and ligand binding. Historically, hydrophobic …

Methyl effects on protein–ligand binding

CS Leung, SSF Leung, J Tirado-Rives… - Journal of medicinal …, 2012 - ACS Publications
The effects of addition of a methyl group to a lead compound on biological activity are
examined. A literature analysis of> 2000 cases reveals that an activity boost of a factor of 10 …

Advances in atomic force microscopy for probing polymer structure and properties

D Wang, TP Russell - Macromolecules, 2018 - ACS Publications
Over the past 30 years, atomic force microscopy (AFM) has played an important role in
elucidating the structure and properties of polymer surfaces. AFM-based techniques have …

Understanding hydrophobic effects: Insights from water density fluctuations

NB Rego, AJ Patel - Annual Review of Condensed Matter …, 2022 - annualreviews.org
The aversion of hydrophobic solutes for water drives diverse interactions and assemblies
across materials science, biology, and beyond. Here, we review the theoretical …

Poly (ethylene glycol) becomes a supra-polyelectrolyte by capturing hydronium ions in water

N Cao, Y Zhao, H Chen, J Huang, M Yu, Y Bao… - …, 2022 - ACS Publications
Poly (ethylene glycol)(PEG) has been widely used for decades as a “gold standard” in
bioconjugation, nanomedicine, and antifouling. Although being extensively studied since …

Water-mediated hydrophobic interactions

D Ben-Amotz - Annual review of physical chemistry, 2016 - annualreviews.org
Hydrophobic interactions are driven by the combined influence of the direct attraction
between oily solutes and an additional water-mediated interaction whose magnitude (and …

Environment-dependent single-chain mechanics of synthetic polymers and biomacromolecules by atomic force microscopy-based single-molecule force spectroscopy …

Y Bao, Z Luo, S Cui - Chemical Society Reviews, 2020 - pubs.rsc.org
“The Tao begets the One. One begets all things of the world.” This quote from Tao Te Ching
is still inspiring for scientists in chemistry and materials science: The “One” can refer to a …