A room‐temperature, visible‐light‐driven N‐centered iminyl radical‐mediated and redox‐
neutral C− C single bond cleavage/radical addition cascade reaction of oxime esters and …

Palladium-catalyzed C H activation/C O bond-forming reactions have emerged as
attractive tools for organic synthesis. Typically, these reactions require strong chemical …

Benzoxazines and benzoxazepines are nitrogen and oxygen‐containing six and seven‐
membered benzo‐fused heterocyclic scaffolds, respectively. Benzoxazepines and …

Benzocyclobutenones are an intriguing class of four-membered-ring ketones that have been
used extensively as powerful synthetic intermediates in organic synthesis. Their high …

Seven! The title reaction can be described as an intermolecular annulation involving tandem
C H activation, cyclization to give the seven‐membered ring, and condensation steps …

Strain-promoted “click” chemistry is used to post-synthetically modify the pore walls of azide-
functionalized mesoporous bio-MOF-100 (N 3-bio-MOF-100). The reactions proceed in high …

The first transition-metal-free catalytic protocol for controlled reduction of amide functions
using cheap and bench-stable hydrosilanes as reducing agents has been established. By …

A novel transformation for the construction of Csp3–Csp bonds was achieved via a photo-
induced copper-catalysed C–C bond cleavage. This approach was applied to prepare a …

Wittig olefination at hetero-benzylic positions for electron-deficient and electron-rich
heterocycles has been studied. The electronic effects of some commonly used protective …

A synthesis of azepines by the expansion of pyridine rings promoted by iodine in air is
reported. The scope of the method is demonstrated with 27 examples. Two iodinations are …