Comprehensive structural, infrared spectroscopic and kinetic investigations of the roles of the active-site arginine in bidirectional hydrogen activation by the [NiFe] …
The active site of [NiFe]-hydrogenases contains a strictly-conserved pendant arginine, the
guanidine head group of which is suspended immediately above the Ni and Fe atoms …
guanidine head group of which is suspended immediately above the Ni and Fe atoms …