Advances in materials and applications of inorganic electrides

H Hosono, M Kitano - Chemical Reviews, 2021 - ACS Publications
Electrides are materials in which electrons serve as anions. Here, the concept of inorganic
electrides is extended in several respects: from ionic crystals to intermetallic compounds in …

Review on selective hydrogenation of nitroarene by catalytic, photocatalytic and electrocatalytic reactions

J Song, ZF Huang, L Pan, K Li, X Zhang, L Wang… - Applied Catalysis B …, 2018 - Elsevier
Selective catalytic hydrogenation of nitroarenes is of great importance for dyestuff and
pharmaceutical industry. A critical step toward the rational design of targeted catalysts is to …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Ceria-based materials for thermocatalytic and photocatalytic organic synthesis

X Huang, K Zhang, B Peng, G Wang, M Muhler… - Acs …, 2021 - ACS Publications
Value-added chemicals, fuels, and pharmaceuticals synthesized by organic transformation
from raw materials via catalytic techniques have attracted enormous attention in the past few …

Reaction product-driven restructuring and assisted stabilization of a highly dispersed Rh-on-ceria catalyst

G Yan, Y Tang, Y Li, Y Li, L Nguyen, T Sakata… - Nature Catalysis, 2022 - nature.com
Understanding the structural dynamics of a catalyst under reaction conditions is challenging
but crucial regarding catalyst design. Here, by a combination of in situ/operando …

Design of effective catalysts for selective alkyne hydrogenation by doping of ceria with a single-atom promotor

C Riley, S Zhou, D Kunwar, A De La Riva… - Journal of the …, 2018 - ACS Publications
Since the discovery that ceria is an active catalyst for selective hydrogenation of alkynes,
there has been much debate on the catalytic mechanism. In this work, we propose, based on …

Hydrogenolysis of Lignin Model Compounds on Ni Nanoparticles Surrounding the Oxygen Vacancy of CeO2

J Xie, Y Xi, W Gao, H Zhang, Y Wu, R Zhang… - ACS …, 2023 - ACS Publications
The cleavage of C–O bonds presents the crucial step for realizing the depolymerization of
lignin. Herein, we report that Ni nanoparticles (NiNPs) supported on CeO2 with oxygen …

Distribution and Valence State of Ru Species on CeO2 Supports: Support Shape Effect and Its Influence on CO Oxidation

J Li, Z Liu, DA Cullen, W Hu, J Huang, L Yao… - Acs …, 2019 - ACS Publications
In this work, ruthenium (Ru) catalysts supported on CeO2 nanorods (NR), nanocubes (NC),
and nanoctahedra (NO) were comparatively investigated to correlate the shape and …

Raman spectroscopy as a powerful tool to characterize ceria-based catalysts

S Loridant - Catalysis Today, 2021 - Elsevier
A review. CeO 2 is widely used and investigated as an oxide catalyst or support due to its
unique redox property of oxygen storage and release. In this paper, the different …

Hydrogen Spillover to Oxygen Vacancy of TiO2–xHy/Fe: Breaking the Scaling Relationship of Ammonia Synthesis

C Mao, J Wang, Y Zou, G Qi, JY Yang Loh… - Journal of the …, 2020 - ACS Publications
Optimizing kinetic barriers of ammonia synthesis to reduce the energy intensity has recently
attracted significant research interest. The motivation for the research is to discover means …