Surface processes on interstellar amorphous solid water: Adsorption, diffusion, tunneling reactions, and nuclear-spin conversion

T Hama, N Watanabe - Chemical reviews, 2013 - ACS Publications
Since we intend to review experimental and theoretical studies of physicochemical
processes occurring on cosmic dust grains in very cold regions in space, we start with a brief …

Hydrogen‐atom tunneling reactions in solid para‐hydrogen and their applications to astrochemistry

KA Haupa, PR Joshi, YP Lee - Journal of the Chinese …, 2022 - Wiley Online Library
H‐atom tunneling reactions play important roles in astrochemistry, but an understanding of
these reactions is still in its infancy. The unique properties associated with quantum solid …

Nuclear spin conservation enables state-to-state control of ultracold molecular reactions

MG Hu, Y Liu, MA Nichols, L Zhu, G Quéméner… - Nature Chemistry, 2021 - nature.com
Quantum-state control of reactive systems has enabled microscopic probes of underlying
interaction potentials and the alteration of reaction rates using quantum statistics. However …

Infrared spectra of free radicals and protonated species produced in para-hydrogen matrices

M Bahou, P Das, YF Lee, YJ Wu, YP Lee - … Chemistry Chemical Physics, 2014 - pubs.rsc.org
The quantum solid para-hydrogen (p-H2) has emerged as a new host for matrix isolation
experiments. Among several unique characteristics, the diminished cage effect enables the …

Spectroscopy of prospective interstellar ions and radicals isolated in para-hydrogen matrices

M Tsuge, CY Tseng, YP Lee - Physical Chemistry Chemical Physics, 2018 - pubs.rsc.org
para-Hydrogen (p-H2) serves as a new host in matrix-isolation experiments for an
investigation of species of astrochemical interest. Protonated and mono-hydrogenated …

Ultraviolet Photodissociation of Proteinogenic Amino Acids

B Moore, K Mahoney, MF Zeng… - Journal of the …, 2023 - ACS Publications
The ultraviolet photochemistry of the amino acids glycine, leucine, proline, and serine in
their neutral forms was investigated using parahydrogen matrix-isolation spectroscopy …

Infrared spectroscopy of chemically doped solid parahydrogen

K Yoshioka, PL Raston… - International Reviews in …, 2006 - Taylor & Francis
This review article presents an overview of recent infrared spectroscopic studies of chemical
species trapped in solid parahydrogen at liquid helium temperatures. An overriding theme …

Hydrocarboxyl Radical as a Product of α-Alanine Ultraviolet Photolysis

B Moore, SY Toh, YTA Wong, T Bashiri… - The Journal of …, 2021 - ACS Publications
UV photodissociation of α-alanine was studied by parahydrogen matrix isolation infrared
spectroscopy. The temporal behavior of Fourier transform infrared spectra revealed that UV …

Significant Chiral Asymmetry Observed in Neutral Amino Acid Ultraviolet Photolysis

B Moore, L Zeng, P Djuricanin, IR Cooke… - Journal of the …, 2024 - ACS Publications
The origin of homochirality in biological organisms remains an open question. Some
suggest that its origin might be extraterrestrial, specifically due to the exposure of chiral …

Photodissociation of N-methylformamide isolated in solid parahydrogen

M Ruzi, DT Anderson - The Journal of chemical physics, 2012 - pubs.aip.org
We report FTIR studies of the 193 nm photodecomposition of N-methylformamide (NMF)
isolated in solid parahydrogen (pH 2) matrices at 1.9 K. By studying the detailed …