Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …

The core N− H units of planar porphyrins are often inaccessible to forming hydrogen‐
bonding complexes with acceptor molecules. This is due to the fact that the amine moieties …

It is crucial and desirable to develop green and high-efficient strategies to regulate solid-
state structures and their related material properties. However, relative to solution, it is more …

Porphyrins are large π-aromatic systems that can complex metal ions from all across the
periodic table. The resulting metalloporphyrins are readily tunable with regards to analyte …

Free-base corroles have long been known to be acidic, readily undergoing deprotonation by
mild bases and in polar solvents. The conjugate base, however, has not been structurally …

Tris-and tetrakis-β-trifluoromethylated gallium (3CF3-Ga, 4CF3-Ga) and aluminum (3CF3-Al,
4CF3-Al) corrole systems were synthesized by a facile “one-pot” approach from the …

An eight-member series of CF3-substituted difluorophosphorus corroles was prepared for
establishing a structure–activity profile of these high-potential photosensitizers. It consisted …

Replacement of the meso methine carbon atoms of porphyrins with heteroatoms is a
powerful strategy for tuning their optical and electronic properties. In particular, 5 …

Hazardous waste dewatering is important for volume reduction and further treatment.
Hazardous organic wastes with low ratio of free to bound water, and low flash point are …

Although a cis tautomer has long been invoked as an intermediate in porphyrin tautomerism,
the first such species was only recently isolated and structurally characterized in the form of …