Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Importance of size and contact structure of gold nanoparticles for the genesis of unique catalytic processes

T Ishida, T Murayama, A Taketoshi, M Haruta - Chemical reviews, 2019 - ACS Publications
Since the discovery of catalysis by Au nanoparticles (NPs), unique catalytic features of Au
have appeared that are greatly different from those of Pd and Pt. In this Review, we aimed to …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Defined metal atom aggregates precisely incorporated into metal–organic frameworks

KL Kollmannsberger, L Kronthaler… - Chemical Society …, 2022 - pubs.rsc.org
Nanosized metal aggregates (MAs), including metal nanoparticles (NPs) and nanoclusters
(NCs), are often the active species in numerous applications. In order to maintain the active …

Counting electrons on supported nanoparticles

Y Lykhach, SM Kozlov, T Skála, A Tovt, V Stetsovych… - Nature materials, 2016 - nature.com
Electronic interactions between metal nanoparticles and oxide supports control the
functionality of nanomaterials, for example, the stability, the activity and the selectivity of …

Ultrastable single-atom gold catalysts with strong covalent metal-support interaction (CMSI)

B Qiao, JX Liang, A Wang, CQ Xu, J Li, T Zhang, JJ Liu - Nano Research, 2015 - Springer
Supported noble metal nanoparticles (including nanoclusters) are widely used in many
industrial catalytic processes. While the finely dispersed nanostructures are highly active …

Catalysis by doped oxides

EW McFarland, H Metiu - Chemical reviews, 2013 - ACS Publications
Metal oxide catalysts have numerous industrial applications. 1− 7 In addition, oxides
catalyze many important reactions whose conversion or selectivity is too low to be …

Modeling Single‐Atom Catalysis

G Di Liberto, G Pacchioni - Advanced Materials, 2023 - Wiley Online Library
Electronic structure calculations represent an essential complement of experiments to
characterize single‐atom catalysts (SACs), consisting of isolated metal atoms stabilized on a …

Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity

BR Cuenya, F Behafarid - Surface Science Reports, 2015 - Elsevier
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …

Tailoring the catalytic properties of metal nanoparticles via support interactions

M Ahmadi, H Mistry… - The Journal of Physical …, 2016 - ACS Publications
The development of new catalysts for energy technology and environmental remediation
requires a thorough knowledge of how the physical and chemical properties of a catalyst …