A comparative study of the concerted hydrolysis of H-, CF3-, CH3-, and Ph-substituted N-
sulfinylamines (R− NSO) and isocyanates (R− NCO) was performed using B3LYP/6-31+ G …

The 17O NMR shift values δo of 20 sulfinylamines R–NSO 2 and of 14 sulfines RR′ CSO 3
(R and R′ mostly arene groups) were compared with those of the isoelectronic SO21. They …

N-sulfinyl-benzeneamine, O S N–C6H5, was studied by spectroscopic and quantum
chemical methods. It was shown that the ground state exhibits a planar structure with a Z …

The synthesis of o-fluorosulfinylaniline is reported with the aim to complete the fluorinated
sulfinylaniline series. The FT-IR and Raman spectra of o-fluorosulfinylaniline are recorded …

We present a computational study on the concerted hydrolysis of several classes of N-
sulfinylamines of generic formula R− N S O, such as the-amines themselves (R− NSO) …

According to X-ray diffraction data, N, N'-disulfinyl-1, 2-diaminobenzene in crystal exists as a
planar Z, Z isomer. On heating or under the action of catalytic amounts of water, as well as in …

The synthesis of m-fluorosulfinylaniline together with a tentative assignment of the
vibrational, NMR and mass spectra are reported. Quantum chemical calculations predict two …

The quantum theory of “atoms in molecules”(AIM) has been employed for an investigation of
the sulfur–oxygen bond in CH3–NSO and CH3–NH–NSO. A comparison with the SO bond …

Natural abundance 17O and 13C NMR spectra for eleven diarylketenes are reported. 17O
shifts show invariance with para substitution and a shielding due to ortho substitution. A …

The study of substitution effects on the structural and vibrational properties of para
substituted sulfinylanilines proceeds a step forward with the study of p …