Recent advances on high-nuclear polyoxometalate clusters

JC Liu, JW Zhao, C Streb, YF Song - Coordination Chemistry Reviews, 2022 - Elsevier
The design and construction of high-nuclear polyoxometalate (POM) clusters remain a
severe challenge, but attract significant interest on account of their impressive structural …

Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices

DL Long, E Burkholder, L Cronin - Chemical Society Reviews, 2007 - pubs.rsc.org
Polyoxometalates represent a diverse range of molecular clusters with an almost unmatched
range of physical properties and the ability to form structures that can bridge several length …

Self‐assembled artificial ion‐channels toward natural selection of functions

S Zheng, L Huang, Z Sun… - Angewandte Chemie …, 2021 - Wiley Online Library
Owing to their significant physiological functions, especially as selective relays for
translocation of physiological relevant species through cellular membranes, natural ion …

From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry

A Müller, P Gouzerh - Chemical Society Reviews, 2012 - pubs.rsc.org
Following Nature's lessons, today chemists can cross the boundary of the small molecule
world to construct multifunctional and highly complex molecular nano-objects up to protein …

Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly

CP Pradeep, DL Long, L Cronin - Dalton Transactions, 2010 - pubs.rsc.org
The synthetic engineering of anionic polyoxometalate (POM) clusters with predefined
properties tailored to specific applications is a great challenge using routine “one-pot” POM …

Hybrid organic–inorganic polyoxometalates: functionalization of VIV/VV nanosized clusters to produce molecular capsules

JM Breen, W Schmitt - Angewandte Chemie International Edition, 2008 - pure.qub.ac.uk
Functionalization of polyoxovanadate clusters using phosphonate and arsonate ligands
results in molecular capsules (see structure; green V, purple P, red O, black C). Through the …

[PDF][PDF] From Scheele and Berzelius to Müller

P Gouzerh, M Che - l'actualité chimique, 2006 - new.societechimiquedefrance.fr
This review provides a survey of polyoxometalate chemistry with special emphasis on its
history, and special attention to Souchay's and Müller's contributions. Polyoxometalates are …

Keggin polyoxometalates encapsulated in molybdenum-iron-type Keplerate nanoball as efficient and cost-effective catalysts in the oxidative desulfurization of sulfides

H Taghiyar, B Yadollahi - Science of The Total Environment, 2020 - Elsevier
In this work, the catalytic activity of core-shell-type polyoxometalate (POM) composites,
comprised from Keggin POMs encapsulated in Mo 72 Fe 30 Keplerate, in the oxidation of …

Polyoxometalates

MT Pope - Encyclopedia of Inorganic Chemistry, 2006 - Wiley Online Library
The elements of groups 5 and 6, especially vanadium, molybdenum, and tungsten in their
highest oxidation states, form a vast range of polyoxoanions that can incorporate most other …

Keggin polyoxoanions in aqueous solution: Ion pairing and its effect on dynamic properties by molecular dynamics simulations

F Leroy, P Miró, JM Poblet, C Bo… - The Journal of Physical …, 2008 - ACS Publications
The dynamics of Keggin polyoxoanions in aqueous solution in the presence of monovalent
cations is analyzed through molecular dynamics simulations. Together with structural …