Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Emerging trends in polymerization-induced self-assembly

NJW Penfold, J Yeow, C Boyer, SP Armes - ACS Macro Letters, 2019 - ACS Publications
In this Perspective, we summarize recent progress in polymerization-induced self-assembly
(PISA) for the rational synthesis of block copolymer nanoparticles with various …

Multiblock copolymer synthesis via RAFT emulsion polymerization

GKK Clothier, TR Guimarães, SW Thompson… - Chemical Society …, 2023 - pubs.rsc.org
A multiblock copolymer is a polymer of a specific structure that consists of multiple covalently
linked segments, each comprising a different monomer type. The control of the monomer …

Red-light-driven atom transfer radical polymerization for high-throughput polymer synthesis in open air

X Hu, G Szczepaniak… - Journal of the …, 2023 - ACS Publications
Photoinduced reversible-deactivation radical polymerization (photo-RDRP) techniques offer
exceptional control over polymerization, providing access to well-defined polymers and …

Progress and perspectives beyond traditional RAFT polymerization

MD Nothling, Q Fu, A Reyhani… - Advanced …, 2020 - Wiley Online Library
The development of advanced materials based on well‐defined polymeric architectures is
proving to be a highly prosperous research direction across both industry and academia …

Machine learning on a robotic platform for the design of polymer–protein hybrids

MJ Tamasi, RA Patel, CH Borca, S Kosuri… - Advanced …, 2022 - Wiley Online Library
Polymer–protein hybrids are intriguing materials that can bolster protein stability in non‐
native environments, thereby enhancing their utility in diverse medicinal, commercial, and …

PET-RAFT polymerization: Mechanistic perspectives for future materials

ML Allegrezza, D Konkolewicz - ACS Macro Letters, 2021 - ACS Publications
In the past decade, photochemistry has emerged as a growing area in organic and polymer
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …

SI-PET-RAFT: surface-initiated photoinduced electron transfer-reversible addition–fragmentation chain transfer polymerization

M Li, M Fromel, D Ranaweera, S Rocha… - ACS Macro …, 2019 - ACS Publications
In this communication, surface-initiated photoinduced electron transfer-reversible addition–
fragmentation chain transfer polymerization (SI-PET-RAFT) is introduced. SI-PET-RAFT …

Guiding the design of organic photocatalyst for PET-RAFT polymerization: halogenated xanthene dyes

C Wu, N Corrigan, CH Lim, K Jung, J Zhu… - …, 2018 - ACS Publications
By examining structurally similar halogenated xanthene dyes, this study establishes a
guiding principle for resolving structure–property–performance relationships in the …

Visible light photoinitiating systems by charge transfer complexes: Photochemistry without dyes

P Garra, JP Fouassier, S Lakhdar, Y Yagci… - Progress in Polymer …, 2020 - Elsevier
Visible light induced synthesis generally involves i) dyes or chromophores with potential
photocleavable bonds (Type I photoinitiator), ii) hydrogen abstractions (Type II photoinitiator) …