Nonaqueous Electrochemistry of Uranium Complexes: A Guide to Structure–Reactivity Tuning

J Riedhammer, DP Halter, K Meyer - Chemical Reviews, 2023 - ACS Publications
Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …

Divalent metallocenes of the lanthanides–a guideline to properties and reactivity

S Schäfer, S Kaufmann, ES Rösch… - Chemical Society …, 2023 - pubs.rsc.org
Since the discovery in the early 1980s, the soluble divalent metallocenes of lanthanides
have become a steadily growing field in organometallic chemistry. The predominant part of …

The vitality of uranium molecular chemistry at the dawn of the XXIst century

M Ephritikhine - Dalton Transactions, 2006 - pubs.rsc.org
The intent of this Dalton Perspective is to highlight the recent advances in uranium
molecular chemistry, with the results reported during the 2000–2006 period. This discipline …

Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVIO–LnIII Bonding …

C Volkringer, N Henry, S Grandjean… - Journal of the American …, 2012 - ACS Publications
A series of uranyl and lanthanide (trivalent Ce, Nd) mellitates (mel) has been hydrothermally
synthesized in aqueous solvent. Mixtures of these 4f and 5f elements also revealed the …

Magnetic exchange coupling in actinide-containing molecules

JD Rinehart, TD Harris, SA Kozimor… - Inorganic …, 2009 - ACS Publications
Recent progress in the assembly of actinide-containing coordination clusters has generated
systems in which the first glimpses of magnetic exchange coupling can be recognized. Such …

Electrochemical studies of tris (cyclopentadienyl) thorium and uranium complexes in the+ 2,+ 3, and+ 4 oxidation states

JC Wedal, JM Barlow, JW Ziller, JY Yang… - Chemical science, 2021 - pubs.rsc.org
Electrochemical measurements on tris (cyclopentadienyl) thorium and uranium compounds
in the+ 2,+ 3, and+ 4 oxidation states are reported with C5H3 (SiMe3) 2, C5H4SiMe3, and …

Probing the chemistry, electronic structure and redox energetics in organometallic pentavalent uranium complexes

CR Graves, AE Vaughn, EJ Schelter, BL Scott… - Inorganic …, 2008 - ACS Publications
A series of organometallic pentavalent uranium complexes of the general formula (C5Me5)
2U (= N-2, 6-i Pr2-C6H3)(Y)(Y= monoanionic, non-halide ligand) have been prepared using …

Series of mixed uranyl–lanthanide (Ce, Nd) organic coordination polymers with aromatic polycarboxylates linkers

I Mihalcea, C Volkringer, N Henry, T Loiseau - Inorganic chemistry, 2012 - ACS Publications
Three series of mixed uranyl-lanthanide (Ce or Nd) carboxylate coordination polymers have
been successfully synthesized by means of a hydrothermal route using either conventional …

Systematic studies of early actinide complexes: Uranium (IV) fluoroketimides

EJ Schelter, P Yang, BL Scott, JD Thompson… - Inorganic …, 2007 - ACS Publications
The reaction of (C5Me5) 2U (CH3) 2 with 2 equiv of N⋮ C− ArF gives the fluorinated
uranium (IV) bis (ketimide) complexes (C5Me5) 2U [− NC (CH3)(ArF)] 2 [where ArF= 2-F …

Self‐Assembly of a 3d–5f Trinuclear Single‐Molecule Magnet from a Pentavalent Uranyl Complex

L Chatelain, JPS Walsh, J Pécaut, F Tuna… - Angewandte …, 2014 - Wiley Online Library
Mixed‐metal uranium compounds are very attractive candidates in the design of single‐
molecule magnets (SMMs), but only one 3d–5f hetero‐polymetallic SMM containing a …