Organoboron-mediated polymerizations

YY Zhang, GW Yang, C Lu, XF Zhu, Y Wang… - Chemical Society …, 2024 - pubs.rsc.org
The scientific community has witnessed extensive developments and applications of
organoboron compounds as synthetic elements and metal-free catalysts for the construction …

Poly (Propylene Carbonate)-Based Biodegradable and Environment-Friendly Materials for Biomedical Applications

L Wang, Y Li, J Yang, Q Wu, S Liang, Z Liu - International Journal of …, 2024 - mdpi.com
Poly (propylene carbonate)(PPC) is an emerging “carbon fixation” polymer that holds the
potential to become a “biomaterial of choice” in healthcare owing to its good …

Biobased Thermoplastic Elastomers Derived from Citronellyl Glycidyl Ether, CO2, and Polylactide

S Schüttner, C Gardiner, FS Petrov, N Fotaras… - …, 2023 - ACS Publications
Biodegradability and biobased feedstocks are key requirements for sustainable materials.
This work presents the synthesis of PLLA-b-PCitroGEC di-and triblock copolymers …

Toward stereo-and sequence-defined block copolymers via a three-site organocatalyst

X Geng, Z Liu, C Zhang, X Zhang - Macromolecules, 2023 - ACS Publications
The development of sustainable polymers as candidates to replace petroleum-based
plastics is a priority, but still a grand challenge. Here, we report a series of stereo-and …

High Molar Mass Polycarbonates as Closed-Loop Recyclable Thermoplastics

G Rosetto, F Vidal, TM McGuire, RWF Kerr… - Journal of the …, 2024 - ACS Publications
Using carbon dioxide (CO2) to make recyclable thermoplastics could reduce greenhouse
gas emissions associated with polymer manufacturing. CO2/cyclic epoxide ring-opening …

[HTML][HTML] CO2 derived ABA triblock all-polycarbonate thermoplastic elastomer with ultra-high elastic recovery

Y Ren, T Zhang, S Wang, D Han, S Huang, H Guo… - Journal of CO2 …, 2024 - Elsevier
Although triblock polycarbonate thermoplastic elastomers (TPEs) have recently attracted
great interests due to their biodegradability, insufficient attentions have been paid to …

Bulky Phosphazenium Salt Controlling Chemoselective Terpolymerization of Epoxide, Anhydride and CO2: From Well‐Defined Block to Truly Random Copolymers

Y Ma, Z Wang, L Jiang, J Zhang, C Ren… - Angewandte Chemie …, 2024 - Wiley Online Library
Copolymers with precise compositions and controlled sequences are great appealing for
high‐performance polymeric materials, but their synthesis is very challenging. In this study …

Bridging polymer architecture, printability, and properties by digital light processing of block copolycarbonates

KG Schoonover, CM Hsieh, M Sengoden, N Ahmed… - Chemical …, 2024 - pubs.rsc.org
CO2-based aliphatic polycarbonates (aPCs), produced through the alternating
copolymerization of epoxides with CO2, present an appealing option for sustainable …

[HTML][HTML] Modification of the Zn–Co double metal cyanide complex for the synthesis of carbon dioxide–derived poly (ether–carbonate) polyols

Q Wang, Y Zhang, X Li, Q Chen, M Kang, Q Li… - Journal of CO2 …, 2024 - Elsevier
Abstract The Zn–Co double metal cyanide (DMC) complex is regarded as a promising
catalyst for the copolymerization of CO 2 and propylene epoxide (PO). Various methods …

Heat-Resistant CO2-Based Polycarbonate Thermoplastics

J Liu, M Jia, Y Gnanou, X Feng - Macromolecules, 2024 - ACS Publications
Designing biodegradable and sustainable polymeric materials that behave as
thermoplastics with enhanced mechanical properties over a wide range of temperatures …