Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

KP Bryliakov - Chemical reviews, 2017 - ACS Publications
The discovery of simple and efficient catalyst systems for the asymmetric
oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this …

Organocatalytic asymmetric epoxidation and aziridination of olefins and their synthetic applications

Y Zhu, Q Wang, RG Cornwall, Y Shi - Chemical Reviews, 2014 - ACS Publications
Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic
Applications | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In …

Metal-catalyzed epoxidations of alkenes with hydrogen peroxide

BS Lane, K Burgess - Chemical reviews, 2003 - ACS Publications
Hydrogen peroxide is probably the best terminal oxidant after dioxygen with respect to
environmental and economic considerations. 1-4 Indeed, in certain circumstances, it is …

Advances in homogeneous and heterogeneous catalytic asymmetric epoxidation

QH Xia, HQ Ge, CP Ye, ZM Liu, KX Su - Chemical Reviews, 2005 - ACS Publications
Barry Sharpless was awarded the 2001 Nobel Prize as a compliment to his great
contributions in the field of asymmetric epoxidation, which has been recognized as one of …

Reaction progress kinetic analysis: a powerful methodology for mechanistic studies of complex catalytic reactions

DG Blackmond - Angewandte Chemie International Edition, 2005 - Wiley Online Library
Reaction progress kinetic analysis to obtain a comprehensive picture of complex catalytic
reaction behavior is described. This methodology employs in situ measurements and simple …

Asymmetric heterogeneous catalysis

M Heitbaum, F Glorius, I Escher - … Chemie International Edition, 2006 - Wiley Online Library
Limited natural resources and an increasing demand for enantiomerically pure compounds
render catalysis and especially heterogeneous asymmetric catalysis a key technology. The …

Asymmetric catalysis mediated by synthetic peptides

EAC Davie, SM Mennen, Y Xu, SJ Miller - Chemical reviews, 2007 - ACS Publications
Exquisitely selective reactions are ubiquitous in the natural world. In such processes,
enzymes exhibit extraordinary degrees of stereoselectivity and can also display remarkable …

Amino acids and peptides as asymmetric organocatalysts

ER Jarvo, SJ Miller - Tetrahedron, 2002 - Elsevier
Many enzymes are remarkable asymmetric catalysts, performing reactions effectively and
selectively. Aspiring to imitate enzymatic efficiencies, chemists have delved into Nature's …

Sulfones: new reagents in organocatalysis

ANR Alba, X Companyó, R Rios - Chemical Society Reviews, 2010 - pubs.rsc.org
The development of new asymmetric methodologies that afford different structures in an
enantioselective fashion is one of the most exciting goals for chemists nowadays. In this …

Supported chiral catalysts on inorganic materials

CE Song, S Lee - Chemical Reviews, 2002 - ACS Publications
For economic, environmental, and social reasons, the trend toward the application of
optically pure compounds is undoubtedly increasing. Among the various methods to …