Molecular excitation in the interstellar medium: Recent advances in collisional, radiative, and chemical processes

E Roueff, F Lique - Chemical reviews, 2013 - ACS Publications
Our main knowledge about astrophysical environments relies on radiative spectra.
Absorption studies require background sources that are located hapharzadly in …

Reactions at very low temperatures: gas kinetics at a new frontier

IWM Smith - Angewandte Chemie International Edition, 2006 - Wiley Online Library
A new era in chemical kinetics was heralded 20 years ago by the results reported by
Bertrand Rowe, then at the Laboratoire d AØrothermique in Meudon.[1] Using an apparatus …

Benzonitrile as a Proxy for Benzene in the Cold ISM: Low-temperature Rate Coefficients for CN+ C6H6

IR Cooke, D Gupta, JP Messinger… - The Astrophysical …, 2020 - iopscience.iop.org
The low-temperature reaction between CN and benzene (C 6 H 6) is of significant interest in
the astrochemical community due to the recent detection of benzonitrile, the first aromatic …

Experimental studies of gas-phase reactivity in relation to complex organic molecules in star-forming regions

IR Cooke, IR Sims - ACS Earth and Space Chemistry, 2019 - ACS Publications
The field of astrochemistry concerns the formation and abundance of molecules in the
interstellar medium, star-forming regions, exoplanets, and solar system bodies. These …

Laboratory astrochemistry: gas-phase processes

IWM Smith - Annual Review of Astronomy and Astrophysics, 2011 - annualreviews.org
A major aim of astrochemistry is to explain the nature and abundance of the molecules
observed in the interstellar medium (ISM). Three kinds of activity are involved:(a) the …

Reaction kinetics at very low temperatures: laboratory studies and interstellar chemistry

IWM Smith, BR Rowe - Accounts of Chemical Research, 2000 - ACS Publications
Studies of gas-phase processes at temperatures down to 10 K have recently blossomed,
largely through application of the CRESU (cinétique de réaction en ecoulement …

A new, fully ab initio investigation of the system. I. Potential energy surfaces and inelastic scattering

MH Alexander - The Journal of chemical physics, 1999 - pubs.aip.org
We report new coupled-cluster [CCSD (T)] ab initio calculations of the two potential energy
surfaces (PES's) of the Ar–NO complex. Successively larger basis sets are used to …

Neutral–neutral reactions at the temperatures of interstellar clouds: Rate coefficients for reactions of atomic carbon, C (3 P), with O 2, C 2 H 2, C 2 H 4 and C 3 H 6 …

D Chastaing, PL James, IR Sims… - Physical Chemistry …, 1999 - pubs.rsc.org
A CRESU (Cine′ tique de Re′ action en Ecoulement Supersonique Uniforme) apparatus
has been used to measure rate coefficients for the reactions of ground-state carbon atoms, C …

On the accuracy of explicitly correlated methods to generate potential energy surfaces for scattering calculations and clustering: application to the HCl–He complex

Y Ajili, K Hammami, NE Jaidane, M Lanza… - Physical Chemistry …, 2013 - pubs.rsc.org
We closely compare the accuracy of multidimensional potential energy surfaces (PESs)
generated by the recently developed explicitly correlated coupled cluster (CCSD (T)-F12) …

Uniform supersonic chemical reactors: 30 years of astrochemical history and future challenges

A Potapov, A Canosa, E Jiménez… - Angewandte Chemie …, 2017 - Wiley Online Library
The interstellar medium is of great interest to us as the place where stars and planets are
born and from where, probably, the molecular precursors of life came to Earth. Astronomical …