This review covers the main synthetic routes to and the corresponding mechanisms of
phosphoramidate formation. The synthetic routes can be separated into six categories: salt …

Phosphoramide, as an important framework of many biologically active molecules, has
attracted widespread attention in recent decades. It is not only widely used in …

A monoanionic phosphoramide ligand is introduced, which forms a series of lanthanum
complexes with the ligand in both anionic and neutral forms. Stoichiometric control alone …

Aerobic oxidation of a dimethylplatinum (II) complex featuring 1, 1-di (2-pyridyl) ethanol as a
supporting ligand leads to the formation of two unexpected PtIV complexes (in∼ 1: 1 ratio) …

A set of structurally analogous, albeit electronically distinct, phosphamides (1aa-10aa) is
prepared, and the effect of the electronic amendment due to p-substitution has been tested …

The reaction of a Cp* Ir (III) phosphoramidate complex with secondary amines gives amine,
imine-bound Cp* Ir (III) hydride complexes resulting from amine dehydrogenation. These …

De récents travaux ont mis en évidence l'augmentation de l'activité catalytique des
catalyseurs contenant un centre métallique électrophile induit grâce aux ligands. L'insertion …