Covering: up to 2023 The marine environment represents a rich yet challenging source of
novel therapeutics. These challenges are best exemplified by the manzamine class of …

Abstract Skipped dienes (1, 4‐dienes) are widely distributed in a variety of biologically active
natural products. The synthesis of these skipped dienes is a relatively undeveloped area …

A highly enantioselective palladium/l-proline-catalyzed α-arylative desymmetrization of
cyclohexanones was developed. The new strategy for α-arylation reaction led to a series of …

A new catalytic asymmetric desymmetrization reaction for the synthesis of enantioenriched
derivatives of 2‐azabicyclo [3.3. 1] nonane, a key motif common to many alkaloids, has been …

The enantioselective total synthesis of madangamine E has been completed in 30 steps,
enabled by a new catalytic and highly enantioselective desymmetrizing intramolecular …

A stereodivergent strategy for the synthesis of skipped dienes is developed. The method
consists of hydroboration of allenes and Migita–Kosugi–Stille coupling, which allows for …

The passion of total‐and fragments syntheses of natural products always remained one of
the top priorities among the synthetic chemists worldwide. Due their curiosity toward the …

Nitrogen-encompassing bioactive molecules can be regarded as the most frequently cited
moieties, occurring either as natural products or as synthetically constructed chemical …

Full details of a stereodivergent hydroboration of allenes are reported. While hydroboration
of an allene with 9‐BBN provided a thermodynamically stable (E)‐allylic alcohol after …

Summary of main observation and conclusion We describe the full details of our total
synthesis of haliclonin A, a macrocyclic natural product suggested to originate from a …