Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity

BR Cuenya, F Behafarid - Surface Science Reports, 2015 - Elsevier
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …

The driving forces in the inclusion complexation of cyclodextrins

L Liu, QX Guo - Journal of inclusion phenomena and macrocyclic …, 2002 - Springer
The driving forces leading to the inclusion complexation of cyclodextrins were reviewed,
which included the electrostatic interaction, van der Waalsinteraction, hydrophobic …

Win some, lose some: enthalpy-entropy compensation in weak intermolecular interactions.

JD Dunitz - Chemistry & biology, 1995 - europepmc.org
Enthalpy-entropy compensation is a general feature of many chemical reactions and
processes in biological systems, but its origin has remained obscure. A simple …

Kinetics in solids

S Vyazovkin, CA Wight - Annual review of physical chemistry, 1997 - annualreviews.org
▪ Abstract The kinetics of solid state reactions generally cannot be assumed to follow simple
rate laws that are applicable to gas-phase reactions. Nevertheless, a widely practiced …

Selective hydrogenation of ethyne in ethene‐rich streams on palladium catalysts, Part 2: Steady‐state kinetics and effects of palladium particle size, carbon monoxide …

A Borodziński, GC Bond - Catalysis Reviews, 2008 - Taylor & Francis
Developments in the last three decades of kinetics of selective hydrogenation of ethyne in
ethene‐rich streams on palladium catalysts are reviewed. Most of the studies can be …

A unified approach to kinetic processing of nonisothermal data

S Vyazovkin - International journal of chemical kinetics, 1996 - Wiley Online Library
Basic problems of kinetic processing of nonisothermal data ascertained from thermal
analysis measurements can be solved by isoconversional methods. Analysis of the …

The mathematical origins of the kinetic compensation effect: 1. The effect of random experimental errors

PJ Barrie - Physical Chemistry Chemical Physics, 2012 - pubs.rsc.org
The kinetic compensation effect states that there is a linear relationship between Arrhenius
parameters ln A and E for a family of related processes. It is a widely observed phenomenon …

Cavity catalysis: modifying linear free-energy relationship under cooperative vibrational strong coupling

J Lather, ANK Thabassum, J Singh, J George - Chemical science, 2022 - pubs.rsc.org
Here, we used an unconventional idea of cooperative vibrational strong coupling of solute
and solvent molecules to enhance the rate of an esterification reaction. Different derivatives …

Enthalpy-entropy compensation in the slow Arrhenius process

E Thoms, S Napolitano - The Journal of Chemical Physics, 2023 - pubs.aip.org
The Meyer–Neldel compensation law, observed in a wide variety of chemical reactions and
other thermally activated processes, provides a proportionality between the entropic and the …

Computer simulations with explicit solvent: recent progress in the thermodynamic decomposition of free energies and in modeling electrostatic effects

RM Levy, E Gallicchio - Annual review of physical chemistry, 1998 - annualreviews.org
▪ Abstract This review focuses on recent progress in two areas in which computer
simulations with explicit solvent are being applied: the thermodynamic decomposition of free …