Metal-catalyzed reductive coupling has emerged as an alternative to the use of
stoichiometric organometallic reagents in an increasingly diverse range of carbonyl and …

Hydrogenation of alkynes in the presence of carbonyl compounds and imines using cationic
rhodium (I) and iridium (I) precatalysts enables the formation of allylic alcohols and allylic …

Transfer hydrogenation of substituted isatins in the presence of allyl acetate, α-methyl allyl
acetate or 1, 1,-dimethylallene employing an ortho-cyclometallated iridium catalyst modified …

Efficient tertiary alcohol synthesis is currently one of the most rapidly advancing fields in
organic chemistry, and recent powerful catalytic methodologies can provide versatile tertiary …

The addition of organometallic reagents to carbonyl compounds has become a versatile
method for synthesizing tertiary and secondary alcohols via carbon− carbon bond formation …

A copper-catalyzed three-component coupling of 1, 3-dienes, bis (pinacolato) diboron, and
ketones allows for the chemo-, regio-, diastereo-and enantioselective assembly of densely …

The formation of C–C bonds via catalytic hydrogenation and transfer hydrogenation enables
carbonyl and imine addition in the absence of stoichiometric organometallic reagents. In this …

The first highly enantioselective catalytic vinylation of aldimines to furnish allylic amines is
reported. Exposure of aromatic and aliphatic N-arylsulfonyl aldimines 1a− 12a to equal …

Highly enantioselective additions of arylboroxines to simple aryl ketones have been
achieved for the first time with a Rh/(R, R, R, R)‐WingPhos catalyst, thus providing a range …

The first intermolecular carbonyl arylations via transfer hydrogenative reductive coupling are
described. Using rhodium catalysts modified by t Bu2PMe, sodium formate-mediated …