Stereospecific olefin polymerization with chiral metallocene catalysts

HH Brintzinger, D Fischer, R Mülhaupt… - … Edition in English, 1995 - Wiley Online Library
Current studies on novel, metallocenebased catalysts for the polymerization of α‐olefins
have far‐reaching implications for the development of new materials as well as for the …

Selectivity in propene polymerization with metallocene catalysts

L Resconi, L Cavallo, A Fait, F Piemontesi - Chemical Reviews, 2000 - ACS Publications
The outstandingly rapid scientific and technological development of metallocene-based
catalysts for olefin polymerization is a perfect example of the successful application of …

[图书][B] Handbook of fiber chemistry

M Lewin - 2006 - taylorfrancis.com
The Handbook of Fiber Chemistry, Third Edition provides complete coverage of scientific
and technological principles for all major natural and synthetic fibers. Incorporating new …

Microstructure of polypropylene

V Busico, R Cipullo - Progress in Polymer Science, 2001 - Elsevier
For over thirty years after the discovery of stereoselective olefin polymerization in 1954, the
word 'polypropylene'has meant, both scientifically and commercially, little else than the …

Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren

HH Brintzinger, D Fischer, R Mülhaupt… - Angewandte …, 1995 - Wiley Online Library
Untersuchungen an neuen Metallocenkatalysatoren zur Polymerisation von α‐Olefinen
haben gegenwärtig weitreichende Auswirkungen auf die Entwicklung neuer Materialien und …

The catalytic system Ti-complex/MgCl2

PC Barbe, G Cecchin, L Noristi - Catalytical and radical polymerization, 1987 - Springer
Abstract MgCl 2 supported Ziegler-Natta catalysts for the polymerization of olefins have had
recently a spectacular success in simplyfling polymerization processes and improving …

Chain transfer reactions in propylene polymerization with zirconocene catalysts

L Resconi, I Camurati, O Sudmeijer - Topics in Catalysis, 1999 - Springer
The chemical structures of end groups of medium-low molecular weight atactic and isotactic
polypropylenes (a-PP and i-PP), produced with zirconocene/methylalumoxane catalysts …

Polymerization of propene in the presence of MgCl2‐supported Ziegler‐Natta catalysts, 1. The role of ethyl benzoate as “internal” and “external” base

V Busico, P Corradini, L De Martino… - Die …, 1985 - Wiley Online Library
The effect of ethyl benzoate (EB) as a component of the solid catalyst (“internal” base) and/or
of the co‐catalyst (“external” base) on propene polymerization in the presence of different …

Polymerization stereochemistry with Ziegler− Natta catalysts containing dialkylpropane diethers: a tool for understanding internal/external donor relationships

MC Sacchi, F Forlini, I Tritto, P Locatelli, G Morini… - …, 1996 - ACS Publications
A study on a new generation of MgCl2-supported Ziegler− Natta catalysts, which contain
dialkylpropane diethers as internal donors and have the property of producing highly active …

Activation effect of alkoxysilanes as external donors in magnesium chloride-supported Ziegler-Natta catalysts

MC Sacchi, F Forlini, I Tritto, R Mendichi… - …, 1992 - ACS Publications
Three pairs of alkoxysilanes,(a) Me (EtO) 3Si, Ph (EtO) 3Si,(b) Ph2 (MeO) 2Si, Ph2 (EtO)
2Si,(c) Ph2 (EtO) 2Si, Ph (EtO) 3Si, differing only in one parameter, have been used as …