Storing energy with molecular photoisomers

Z Wang, P Erhart, T Li, ZY Zhang, D Sampedro, Z Hu… - Joule, 2021 - cell.com
Some molecular photoisomers can be isomerized to a metastable high-energy state by
exposure to light. These molecules can then be thermally or catalytically converted back to …

Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes …

EY Matveev, VV Avdeeva, KY Zhizhin, EA Malinina… - Inorganics, 2022 - mdpi.com
This review systematizes data on the coordination ability of mono-and disubstituted
derivatives of boron cluster anions and carboranes in complexation with transition metals …

Water-Stable Carborane-Based Eu3+/Tb3+ Metal–Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar …

Z Li, R Núñez, ME Light, E Ruiz, F Teixidor… - Chemistry of …, 2022 - ACS Publications
Luminescent lanthanide metal–organic frameworks (Ln-MOFs) have been shown to exhibit
relevant optical properties of interest for practical applications, though their implementation …

Carboranes in the chemist's toolbox

RN Grimes - Dalton Transactions, 2015 - pubs.rsc.org
Once seldom encountered outside of a few laboratories, carboranes are now everywhere,
playing a role in the development of a broad range of technologies encompassing organic …

A Metal‐Organic Framework Incorporating Eight Different Size Rare‐Earth Metal Elements: Toward Multifunctionality À La Carte

Z Li, XB Li, ME Light, AE Carrillo… - Advanced Functional …, 2023 - Wiley Online Library
Multi‐metallic multivariate (MTV) rare earth (RE) metal− organic frameworks (MOFs) are of
interest for the development of multifunctional materials, however examples with more than …

Enantioselective Synthesis of Chiral-at-Cage o-Carboranes via Pd-Catalyzed Asymmetric B–H Substitution

R Cheng, B Li, J Wu, J Zhang, Z Qiu… - Journal of the …, 2018 - ACS Publications
Carborane cage chirality is an outstanding issue of great interest as the icosahedral
carboranes have wide applications in medicinal and materials chemistry. The synthesis of …

Asymmetric hydroboration of heteroaryl ketones by aluminum catalysis

Y Lebedev, I Polishchuk, B Maity… - Journal of the …, 2019 - ACS Publications
A series of methyl aluminum complexes bearing chiral biphenol-type ligands were found to
be highly active catalysts in the asymmetric reduction of heterocyclic ketones (S/C= 100 …

Rational design of carborane-based Cu 2-paddle wheel coordination polymers for increased hydrolytic stability

Z Li, D Choquesillo-Lazarte, J Fraile, C Viñas… - Dalton …, 2022 - pubs.rsc.org
A new unsymmetric carborane-based dicarboxylic linker provided a 1D Cu2-paddle wheel
coordination polymer (2) with much higher hydrolytic stability than the corresponding 2D …

Synthesis, Structure, and Catalytic Applications for ortho- and meta-Carboranyl Based NBN Pincer-Pd Complexes

MY Tsang, C Vinas, F Teixidor, JG Planas… - Inorganic …, 2014 - ACS Publications
o-and m-Carborane-based NBN pincer palladium complexes (o CB-L1) Pd,(o CB-L2) Pd,
and (m CB-L1) Pd are synthesized in two steps from commercially available starting …

Tuning the architectures and luminescence properties of Cu (I) compounds of phenyl and carboranyl pyrazoles: the impact of 2D versus 3D aromatic moieties in the …

J Soldevila-Sanmartín, E Ruiz… - Journal of Materials …, 2021 - pubs.rsc.org
Incorporation of one or two o-carborane moieties at the backbone of the pyrazole ring was
achieved by lithiation and nucleophilic addition onto the corresponding 3, 5-dimethyl-1-(2 …