Efficient hydrogen generation from aqueous protons through direct conversion of solar
energy is an essential prerequisite of a future hydrogen economy and easily accessible …

In recent years, researchers have shifted their focus towards investigating the redox
properties of ancillary ligand backbones for small‐molecule activation. Several metal …

In this study, we report a pair of electrocatalysts for the hydrogen evolution reaction (HER)
based on the noninnocent ligand diacetyl-2-(4-methyl-3-thiosemicarbazone)-3-(2 …

This work reports on the synthesis and characterization of a series of mononuclear
thiosemicarbazone nickel complexes that display significant catalytic activity for hydrogen …

A series of mononuclear first-row transition metal pyrithione M (pyr) n complexes (M= Ni (II),
Mn (II), n= 2; M= Co (III), Fe (III), n= 3) have been prepared from the reaction of the …

A series of new bis (thiosemicarbazonato) Cu (II) complexes with pendent polyamines,
diacetyl‐(N,‐dimethylethylenediaminothiosemicarbazon…)‐(N'‐methyl‐3‐thio …

The search for alternative non‐noble transition metal catalysts able to evolve hydrogen has
been the focus of intense research. Molecular complexes bearing redox‐active ligands have …

The synthesis of a new nickel (II) coordination complex bearing acenaphthenequinone bis
(thiosemicarbazone),[NiL], a N 2 S 2 tetradentate bis-Schiff base ligand (H 2 L), under reflux …

Molecular catalysts with N 2 S 2 chelates and earth abundant metals have been used in
different applications. With their versatile nature to modulate activity through changes in the …

Five new heteroleptic nickel complexes containing O‐methyldithiophosphate and
aminodiphosphine monosulfide ligands,[Ni ((PPh2)({S} PPh2) NR)(S2P {O} …