We revise the high pressure, high temperature phase diagram of CaCO 3 using Raman
spectroscopy in conjunction with laser heated diamond anvil cell experiments. We confirm …

We show, by single-crystal diffraction studies in laser-heated diamond-anvil cells, that
Ca2CO4 orthocarbonate, which contains CO44− tetrahedra, can be formed already at~ 20 …

The synthesis of a novel type of carbonate, namely of the inorganic pyrocarbonate salt Sr
[C2O5], which contains isolated [C2O5] 2–-groups, significantly extends the crystal chemistry …

Earth carbon cycle shapes the evolution of our planet and our habitats. As a key region of
carbon cycle, subduction zone acts as a sole channel transporting supracrustal carbonate …

The importance for the global carbon cycle, the P–T phase diagram of CaCO3 has been
under extensive investigation since the invention of the high-pressure techniques. However …

We have synthesized the orthocarbonate Sr2CO4, in which carbon is tetrahedrally
coordinated by four oxygen atoms, at moderately high pressures [20 (1) GPa] and high …

Within the framework of the density functional theory (DFT) and the hybrid functional B3LYP
by means of the CRYSTAL17 program code, the wavenumbers and intensities of normal …

We have synthesized the orthocarbonate Sr3 [CO4] O in a laser-heated diamond anvil cell at
20 and 30 GPa by heating to≈ 3000 (300) K. Afterward, we recovered the orthocarbonate …

We have synthesized Pb [C2O5], an inorganic pyrocarbonate salt, in a laser-heated
diamond anvil cell (LH-DAC) at 30 GPa by heating a Pb [CO3]+ CO2 mixture to≈ 2000 …

CaC2O5-I 4̅2 d was obtained by reacting CO2 and CaCO3 at lower Earth mantle
pressures and temperatures ranging between 34 and 45 GPa and between 2000 and 3000 …