Total synthesis of (±)-pallambins C and D

XS Xu, ZW Li, YJ Zhang, XS Peng… - Chemical …, 2012 - pubs.rsc.org
The first total synthesis of (±)-pallambins C and D has been accomplished in a linear 38 step
reaction from (±)-Wieland–Miescher ketone. The key conversions are featured as follows: a …

BF 3-Et 2 O mediated skeletal rearrangements of norbornyl appended cyclopentanediols

CN Rao, FA Khan - Organic & Biomolecular Chemistry, 2015 - pubs.rsc.org
An unusual cascade rearrangement has been noticed as a competitive reaction during the
treatment of norbornyl appended cyclopentanediols with a Lewis acid (LA): a BF3-Et2O …

Synthesis of carbazole analogs via Grob fragmentation of norbornyl α-diketones

K Sravanthi, SK Agrawal, CN Rao, FA Khan - Tetrahedron Letters, 2016 - Elsevier
A regioselective synthesis of carbazole analogs belonging to both the categories of natural
origin, viz., microorganisms and higher plant source is reported. The synthesis of carbazole …

FeCl3 catalyzed 1, 6-conjugate addition of phenol C-nucleophiles: Facile synthesis of diarylmethanes

K Sreenivas, FA Khan - Tetrahedron, 2020 - Elsevier
An efficient synthesis of diarylmethane derivatives from phenol and a p-quinone methide
surrogate cyclohexadienone derivative has been described. This 1, 6-conjugate addition …

1, 6-Conjugate addition of C-nucleophiles to p-quinone methide surrogate: Synthesis of diarylpropanes

K Sreenivas, FA Khan - Tetrahedron, 2019 - Elsevier
Conjugate addition of various carbon nucleophiles to p-quinone methide surrogate is
reported. The active methylene containing C-nucleophiles such as 1, 3-diketones, diesters …

Grob-type fragmentation of 5-oxabicyclo [2.1. 1] hexane system: a strategy for synthesis of annulated and 2, 2, 5-trisubstituted tetrahydrofurans

SH Mahadevegowda, FA Khan - Tetrahedron, 2013 - Elsevier
Acid mediated, efficient Grob-type fragmentation reaction facilitated by vicinal ketal and ester
moieties in variety of 5-oxabicyclo [2.1. 1] hexanes leading to the corresponding annulated …

An unusual formation of diarylmethane scaffolds from 4-(halomethyl) cyclohex-2-enone derivatives

KR Babu, FA Khan - Tetrahedron Letters, 2015 - Elsevier
A facile and efficient base promoted one-pot dimerization of halo cyclohexene derivatives
leading to a de novo synthesis of biologically important diarylmethane and diarylmethanone …

Brønsted acid-induced synthesis of methyl benzofurans via Grob type fragmentation of norbornyl derivatives

K Sravanthi, FA Khan - Tetrahedron Letters, 2020 - Elsevier
An efficient Brønsted acid-induced one-pot syntheses of 2-methylbenzofurans from
norbornyl derivatives have been reported. The construction of new C–O bond proceeds via …

Aromatization-driven Grob-fragmentation approach toward polyazaacenes. Synthesis and amination of multi-functionalized diazapentacenes

TC Chou, JF Cheng, AR Gholap, JJK Huang, JC Chen… - Tetrahedron, 2019 - Elsevier
A general approach toward the synthesis of multi-functionalized diazapentacene derivatives
1, using 1, 2, 3, 4-tetrachloro-5, 5-dimethoxycyclopentadiene (TDCp, 2), a substituted …

Diastereoselective Synthesis of Spirocyclic Dihydrofurans and 1‐Oxaspiro [4.5] decan‐6‐one Derivatives from Norbornyl α‐Diketones

SH Mahadevegowda, FA Khan - European Journal of Organic …, 2015 - Wiley Online Library
A diastereoselective zinc‐mediated propargylation of non‐enolizable norbornyl α‐diketones
and an efficient AgI‐catalyzed cycloisomerization of the resulting α‐keto homopropargyl …